Perovskite-derived structure modulation in the iron sulfate family

Yuanqi Lan; Qi Yan; Xinyuan Zhang; Wenjiao Yao; Chenchen Wang; Chun-Sing Lee; Philip Lightfoot; Yongbing Tang

doi:10.1039/d2cc02242g

Perovskite-derived structure modulation in the iron sulfate family

Yuanqi Lan, Qi Yan, Xinyuan Zhang, Wenjiao Yao^*, Chenchen Wang, Chun-Sing Lee, Philip Lightfoot^*, Yongbing Tang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

We report the first example of a perovskite sulfate [Na₃(H₂O)]Fe(SO₄)₃. Further structure modulation, by dimensional reduction or ligand extension, has resulted in two related layered perovskite-like compounds Na₆Fe(SO₄)₄ and Na₁₂Fe₃(SO₄)₆F₈. Taken together, these results open up a more general strategy for the future design of more complex perovskite-related materials.

Original language	English
Pages (from-to)	7074-7077
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	50
Early online date	6 Jun 2022
DOIs	https://doi.org/10.1039/d2cc02242g
Publication status	Published - 25 Jun 2022

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RADII

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10.1039/d2cc02242g

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Copyright © 2022 The Author(s). This work has been made available online in accordance with publisher policies or with permission. Permission for further reuse of this content should be sought from the publisher or the rights holder. This is the author created accepted manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1039/D2CC02242G
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CSD 2031475, 2050477 & 2099156: Experimental Crystal Structure Determination
Lan, Y. (Creator), Yan, Q. (Creator), Zhang, X. (Creator), Yao, W. (Creator), Wang, C. (Creator), Lee, C.-S. (Creator), Lightfoot, P. (Creator) & Tang, Y. (Creator), Cambridge Crystallographic Data Centre, 2022
DOI: 10.25505/fiz.icsd.cc265xgs, https://dx.doi.org/10.25505/fiz.icsd.cc26tpf5 and one more link, https://dx.doi.org/10.25505/fiz.icsd.cc28gbqt (show fewer)
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title = "Perovskite-derived structure modulation in the iron sulfate family",

abstract = "We report the first example of a perovskite sulfate [Na3(H2O)]Fe(SO4)3. Further structure modulation, by dimensional reduction or ligand extension, has resulted in two related layered perovskite-like compounds Na6Fe(SO4)4 and Na12Fe3(SO4)6F8. Taken together, these results open up a more general strategy for the future design of more complex perovskite-related materials.",

keywords = "RADII",

author = "Yuanqi Lan and Qi Yan and Xinyuan Zhang and Wenjiao Yao and Chenchen Wang and Chun-Sing Lee and Philip Lightfoot and Yongbing Tang",

note = "Funding: Authors acknowledge support from Shenzhen Key Laboratory of Energy Materials for Carbon Neutrality (China). The authors acknowledge support from the National Natural Science Foundation of China (52125105, 22005329, 51972329, 52061160484), the Shenzhen Science and Technology Planning Project (JCYJ20190807172001755, JCYJ20210324101016039, JCYJ20210324101203009), and the Science and Technology Planning Project of Guangdong Province (2019A1515110975, 2021A1515010184, 2019TX05L389).",

year = "2022",

month = jun,

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doi = "10.1039/d2cc02242g",

language = "English",

volume = "58",

pages = "7074--7077",

journal = "Chemical Communications",

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T1 - Perovskite-derived structure modulation in the iron sulfate family

AU - Lan, Yuanqi

AU - Yan, Qi

AU - Zhang, Xinyuan

AU - Yao, Wenjiao

AU - Wang, Chenchen

AU - Lee, Chun-Sing

AU - Lightfoot, Philip

AU - Tang, Yongbing

N1 - Funding: Authors acknowledge support from Shenzhen Key Laboratory of Energy Materials for Carbon Neutrality (China). The authors acknowledge support from the National Natural Science Foundation of China (52125105, 22005329, 51972329, 52061160484), the Shenzhen Science and Technology Planning Project (JCYJ20190807172001755, JCYJ20210324101016039, JCYJ20210324101203009), and the Science and Technology Planning Project of Guangdong Province (2019A1515110975, 2021A1515010184, 2019TX05L389).

PY - 2022/6/25

Y1 - 2022/6/25

N2 - We report the first example of a perovskite sulfate [Na3(H2O)]Fe(SO4)3. Further structure modulation, by dimensional reduction or ligand extension, has resulted in two related layered perovskite-like compounds Na6Fe(SO4)4 and Na12Fe3(SO4)6F8. Taken together, these results open up a more general strategy for the future design of more complex perovskite-related materials.

AB - We report the first example of a perovskite sulfate [Na3(H2O)]Fe(SO4)3. Further structure modulation, by dimensional reduction or ligand extension, has resulted in two related layered perovskite-like compounds Na6Fe(SO4)4 and Na12Fe3(SO4)6F8. Taken together, these results open up a more general strategy for the future design of more complex perovskite-related materials.

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DO - 10.1039/d2cc02242g

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SN - 1359-7345

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SP - 7074

EP - 7077

JO - Chemical Communications

JF - Chemical Communications

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ER -

Perovskite-derived structure modulation in the iron sulfate family

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CSD 2031475, 2050477 & 2099156: Experimental Crystal Structure Determination

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