Performance of octene in fluorous biphasic hydroformylation: octene distribution and reversible transfer between perfluoromethylcyclohexane and nonanal

Yulin Huang; Evangelia Perperi; George Manos; David John Cole-Hamilton

doi:10.1016/j.molcata.2003.08.028

Performance of octene in fluorous biphasic hydroformylation: octene distribution and reversible transfer between perfluoromethylcyclohexane and nonanal

Yulin Huang, Evangelia Perperi, George Manos, David John Cole-Hamilton

Research output: Contribution to journal › Article › peer-review

Abstract

During fluorous biphasic hydroformylation 1-octene is transferred from the fluorous into the organic product phase and then from the product layer back to the fluorous layer again, due to the immiscibility of nonanal with PFMCH. The effect of the temperature and the total amount of octene on the above behaviour were also studied. (C) 2003 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	17-21
Number of pages	5
Journal	Journal of Molecular Catalysis A: Chemical
Volume	210
Issue number	1-2
DOIs	https://doi.org/10.1016/j.molcata.2003.08.028
Publication status	Published - 1 Mar 2004

Keywords

octene
phase behaviour
fluorous biphasic system
hydroformylation
HOMOGENEOUS CATALYSIS
2-PHASE HYDROFORMYLATION
ATOM ECONOMY
WATER
SELECTIVITY
SEPARATION
LIGANDS
CHEMISTRY
SYSTEM
TELOMERIZATION

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10.1016/j.molcata.2003.08.028

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title = "Performance of octene in fluorous biphasic hydroformylation: octene distribution and reversible transfer between perfluoromethylcyclohexane and nonanal",

abstract = "During fluorous biphasic hydroformylation 1-octene is transferred from the fluorous into the organic product phase and then from the product layer back to the fluorous layer again, due to the immiscibility of nonanal with PFMCH. The effect of the temperature and the total amount of octene on the above behaviour were also studied. (C) 2003 Elsevier B.V. All rights reserved.",

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AU - Huang, Yulin

AU - Perperi, Evangelia

AU - Manos, George

AU - Cole-Hamilton, David John

PY - 2004/3/1

Y1 - 2004/3/1

N2 - During fluorous biphasic hydroformylation 1-octene is transferred from the fluorous into the organic product phase and then from the product layer back to the fluorous layer again, due to the immiscibility of nonanal with PFMCH. The effect of the temperature and the total amount of octene on the above behaviour were also studied. (C) 2003 Elsevier B.V. All rights reserved.

AB - During fluorous biphasic hydroformylation 1-octene is transferred from the fluorous into the organic product phase and then from the product layer back to the fluorous layer again, due to the immiscibility of nonanal with PFMCH. The effect of the temperature and the total amount of octene on the above behaviour were also studied. (C) 2003 Elsevier B.V. All rights reserved.

KW - octene

KW - phase behaviour

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KW - hydroformylation

KW - HOMOGENEOUS CATALYSIS

KW - 2-PHASE HYDROFORMYLATION

KW - ATOM ECONOMY

KW - WATER

KW - SELECTIVITY

KW - SEPARATION

KW - LIGANDS

KW - CHEMISTRY

KW - SYSTEM

KW - TELOMERIZATION

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ER -

Performance of octene in fluorous biphasic hydroformylation: octene distribution and reversible transfer between perfluoromethylcyclohexane and nonanal

Abstract

Keywords

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