Performance of octene in fluorous biphasic hydroformylation: octene distribution and reversible transfer between perfluoromethylcyclohexane and nonanal

Yulin Huang, Evangelia Perperi, George Manos, David John Cole-Hamilton

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

During fluorous biphasic hydroformylation 1-octene is transferred from the fluorous into the organic product phase and then from the product layer back to the fluorous layer again, due to the immiscibility of nonanal with PFMCH. The effect of the temperature and the total amount of octene on the above behaviour were also studied. (C) 2003 Elsevier B.V. All rights reserved.

Original languageEnglish
Pages (from-to)17-21
Number of pages5
JournalJournal of Molecular Catalysis A: Chemical
Volume210
Issue number1-2
DOIs
Publication statusPublished - 1 Mar 2004

Keywords

  • octene
  • phase behaviour
  • fluorous biphasic system
  • hydroformylation
  • HOMOGENEOUS CATALYSIS
  • 2-PHASE HYDROFORMYLATION
  • ATOM ECONOMY
  • WATER
  • SELECTIVITY
  • SEPARATION
  • LIGANDS
  • CHEMISTRY
  • SYSTEM
  • TELOMERIZATION

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