Perfluorocarbon liquid under pressure: a medium for gas delivery

Scott C. McKellar; Jorge Sotelo; John P S Mowat; Paul A. Wright; Stephen A. Moggach

doi:10.1039/c5ce01989c

Perfluorocarbon liquid under pressure: a medium for gas delivery

Scott C. McKellar, Jorge Sotelo, John P S Mowat, Paul A. Wright, Stephen A. Moggach^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

A novel method for CO₂ delivery to a porous material is reported, wherein a perfluorocarbon containing dissolved CO₂ has been used as a pressure-transmitting liquid in a high-pressure single-crystal X-ray diffraction experiment. Pressure causes the gas to be squeezed out of the liquid into the host crystal, monitored via a single-crystal to single-crystal phase transition on uptake of CO₂.

Original language	English
Pages (from-to)	1273-1276
Number of pages	4
Journal	CrystEngComm
Volume	18
Issue number	8
Early online date	14 Dec 2015
DOIs	https://doi.org/10.1039/c5ce01989c
Publication status	Published - 28 Feb 2016

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Wright_Perfluorocarbon_CrystEngComm_AM
Copyright 2016 the Authors. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1039/C5CE01989C
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Cite this

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abstract = "A novel method for CO2 delivery to a porous material is reported, wherein a perfluorocarbon containing dissolved CO2 has been used as a pressure-transmitting liquid in a high-pressure single-crystal X-ray diffraction experiment. Pressure causes the gas to be squeezed out of the liquid into the host crystal, monitored via a single-crystal to single-crystal phase transition on uptake of CO2.",

author = "McKellar, {Scott C.} and Jorge Sotelo and Mowat, {John P S} and Wright, {Paul A.} and Moggach, {Stephen A.}",

note = "The authors thank the Royal Society of Edinburgh and the Scottish Government for a fellowship to Dr Stephen A. Moggach, and the Leverhulme Trust for financial support.",

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AU - McKellar, Scott C.

AU - Sotelo, Jorge

AU - Mowat, John P S

AU - Wright, Paul A.

AU - Moggach, Stephen A.

N1 - The authors thank the Royal Society of Edinburgh and the Scottish Government for a fellowship to Dr Stephen A. Moggach, and the Leverhulme Trust for financial support.

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N2 - A novel method for CO2 delivery to a porous material is reported, wherein a perfluorocarbon containing dissolved CO2 has been used as a pressure-transmitting liquid in a high-pressure single-crystal X-ray diffraction experiment. Pressure causes the gas to be squeezed out of the liquid into the host crystal, monitored via a single-crystal to single-crystal phase transition on uptake of CO2.

AB - A novel method for CO2 delivery to a porous material is reported, wherein a perfluorocarbon containing dissolved CO2 has been used as a pressure-transmitting liquid in a high-pressure single-crystal X-ray diffraction experiment. Pressure causes the gas to be squeezed out of the liquid into the host crystal, monitored via a single-crystal to single-crystal phase transition on uptake of CO2.

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Perfluorocarbon liquid under pressure: a medium for gas delivery

Abstract

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