[Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysed alcohol oxidation using molecular oxygen

Vaclav Jurcik; Thibault E. Schmid; Quentin Dumont; Alexandra M. Z. Slawin; Catherine S. J. Cazin

doi:10.1039/c2dt30133d

[Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysed alcohol oxidation using molecular oxygen

Vaclav Jurcik, Thibault E. Schmid, Quentin Dumont, Alexandra M. Z. Slawin, Catherine S. J. Cazin

Research output: Contribution to journal › Article › peer-review

32 Citations (Scopus)

Abstract

A series of [Pd(NHC)(PR3)] complexes quantitatively form [Pd(eta(2)-O-2)(NHC)(PR3)] products when submitted to an dioxygen atmosphere. Synthetic details and structural features of these Pd-peroxo complexes are described. The palladium compounds were found to be efficient catalysts in the oxidation of alcohols into corresponding carbonyl compounds using O-2 or air as oxidant. Reactions proceed at low catalyst loadings with a wide range of alcohols.

Original language	English
Pages (from-to)	12619-12623
Number of pages	5
Journal	Dalton Transactions
Volume	41
Issue number	40
DOIs	https://doi.org/10.1039/c2dt30133d
Publication status	Published - 2012

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10.1039/c2dt30133d

Studies of homogeneous catalysts: Mechanistic studies of homogeneous catalysts
Cazin, C. S. J. (PI)
The Royal Society
6/03/11 → 5/02/12
Project: Standard
Synergistic Ligand Effects in Palladium: Synergistic Ligand Effects in Palladium Catalysis
Cazin, C. S. J. (PI)
EPSRC
13/11/09 → 12/11/10
Project: Standard

Cite this

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title = "[Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysed alcohol oxidation using molecular oxygen",

abstract = "A series of [Pd(NHC)(PR3)] complexes quantitatively form [Pd(eta(2)-O-2)(NHC)(PR3)] products when submitted to an dioxygen atmosphere. Synthetic details and structural features of these Pd-peroxo complexes are described. The palladium compounds were found to be efficient catalysts in the oxidation of alcohols into corresponding carbonyl compounds using O-2 or air as oxidant. Reactions proceed at low catalyst loadings with a wide range of alcohols.",

author = "Vaclav Jurcik and Schmid, {Thibault E.} and Quentin Dumont and Slawin, {Alexandra M. Z.} and Cazin, {Catherine S. J.}",

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language = "English",

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T1 - [Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysed alcohol oxidation using molecular oxygen

AU - Jurcik, Vaclav

AU - Schmid, Thibault E.

AU - Dumont, Quentin

AU - Slawin, Alexandra M. Z.

AU - Cazin, Catherine S. J.

PY - 2012

Y1 - 2012

N2 - A series of [Pd(NHC)(PR3)] complexes quantitatively form [Pd(eta(2)-O-2)(NHC)(PR3)] products when submitted to an dioxygen atmosphere. Synthetic details and structural features of these Pd-peroxo complexes are described. The palladium compounds were found to be efficient catalysts in the oxidation of alcohols into corresponding carbonyl compounds using O-2 or air as oxidant. Reactions proceed at low catalyst loadings with a wide range of alcohols.

AB - A series of [Pd(NHC)(PR3)] complexes quantitatively form [Pd(eta(2)-O-2)(NHC)(PR3)] products when submitted to an dioxygen atmosphere. Synthetic details and structural features of these Pd-peroxo complexes are described. The palladium compounds were found to be efficient catalysts in the oxidation of alcohols into corresponding carbonyl compounds using O-2 or air as oxidant. Reactions proceed at low catalyst loadings with a wide range of alcohols.

U2 - 10.1039/c2dt30133d

DO - 10.1039/c2dt30133d

M3 - Article

SN - 1477-9226

VL - 41

SP - 12619

EP - 12623

JO - Dalton Transactions

JF - Dalton Transactions

IS - 40

ER -

[Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysed alcohol oxidation using molecular oxygen

Abstract

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Projects

Studies of homogeneous catalysts: Mechanistic studies of homogeneous catalysts

Synergistic Ligand Effects in Palladium: Synergistic Ligand Effects in Palladium Catalysis

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