[Pd(IPr*OMe )(cin)Cl] (cin=Cinnamyl): a versatile catalyst for C-N and C-C bond formation

Gulluzar Bastug; Steven Patrick Nolan

doi:10.1021/om500026s

[Pd(IPr*^OMe )(cin)Cl] (cin=Cinnamyl): a versatile catalyst for C-N and C-C bond formation

Gulluzar Bastug, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

[Pd(IPr*OMe)(cin)(Cl)] provides high catalytic activity for Buchwald−Hartwig cross-coupling reactions of sterically demanding aryl chlorides with sterically hindered and deactivated aniline derivatives. This catalyst also proved efficient in Suzuki−Miyaura reactions, thus allowing the preparation of tetra-ortho-substituted biaryls. The Kumada−Corriu coupling has also been investigated using this palladium N-heterocyclic carbene (NHC) catalyst.

Original language	English
Pages (from-to)	1253-1258
Number of pages	6
Journal	Organometallics
Volume	33
Issue number	5
Early online date	14 Feb 2014
DOIs	https://doi.org/10.1021/om500026s
Publication status	Published - 10 Mar 2014

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title = "[Pd(IPr*OMe )(cin)Cl] (cin=Cinnamyl): a versatile catalyst for C-N and C-C bond formation",

abstract = "[Pd(IPr*OMe)(cin)(Cl)] provides high catalytic activity for Buchwald−Hartwig cross-coupling reactions of sterically demanding aryl chlorides with sterically hindered and deactivated aniline derivatives. This catalyst also proved efficient in Suzuki−Miyaura reactions, thus allowing the preparation of tetra-ortho-substituted biaryls. The Kumada−Corriu coupling has also been investigated using this palladium N-heterocyclic carbene (NHC) catalyst.",

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year = "2014",

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doi = "10.1021/om500026s",

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T2 - a versatile catalyst for C-N and C-C bond formation

AU - Bastug, Gulluzar

AU - Nolan, Steven Patrick

PY - 2014/3/10

Y1 - 2014/3/10

N2 - [Pd(IPr*OMe)(cin)(Cl)] provides high catalytic activity for Buchwald−Hartwig cross-coupling reactions of sterically demanding aryl chlorides with sterically hindered and deactivated aniline derivatives. This catalyst also proved efficient in Suzuki−Miyaura reactions, thus allowing the preparation of tetra-ortho-substituted biaryls. The Kumada−Corriu coupling has also been investigated using this palladium N-heterocyclic carbene (NHC) catalyst.

AB - [Pd(IPr*OMe)(cin)(Cl)] provides high catalytic activity for Buchwald−Hartwig cross-coupling reactions of sterically demanding aryl chlorides with sterically hindered and deactivated aniline derivatives. This catalyst also proved efficient in Suzuki−Miyaura reactions, thus allowing the preparation of tetra-ortho-substituted biaryls. The Kumada−Corriu coupling has also been investigated using this palladium N-heterocyclic carbene (NHC) catalyst.

U2 - 10.1021/om500026s

DO - 10.1021/om500026s

M3 - Article

SN - 0276-7333

VL - 33

SP - 1253

EP - 1258

JO - Organometallics

JF - Organometallics

IS - 5

ER -

[Pd(IPr*OMe )(cin)Cl] (cin=Cinnamyl): a versatile catalyst for C-N and C-C bond formation

Abstract

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[Pd(IPr*^OMe )(cin)Cl] (cin=Cinnamyl): a versatile catalyst for C-N and C-C bond formation