[Pd(IPr*OMe )(cin)Cl] (cin=Cinnamyl): a versatile catalyst for C-N and C-C bond formation

Gulluzar Bastug, Steven Patrick Nolan

Research output: Contribution to journalArticlepeer-review

86 Citations (Scopus)


[Pd(IPr*OMe)(cin)(Cl)] provides high catalytic activity for Buchwald−Hartwig cross-coupling reactions of sterically demanding aryl chlorides with sterically hindered and deactivated aniline derivatives. This catalyst also proved efficient in Suzuki−Miyaura reactions, thus allowing the preparation of tetra-ortho-substituted biaryls. The Kumada−Corriu coupling has also been investigated using this palladium N-heterocyclic carbene (NHC) catalyst.
Original languageEnglish
Pages (from-to)1253-1258
Number of pages6
Issue number5
Early online date14 Feb 2014
Publication statusPublished - 10 Mar 2014


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