Panchromic Cationic Iridium(III) Complexes

Kamrul Hasan, Eli Zysman-Colman*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

33 Citations (Scopus)

Abstract

We report the synthesis, X-ray structures, and optoelectronic characterization of two cationic iridium complexes bearing bis[(4-methoxyphenyl)imino]acenaphthene ligands. These complexes exhibited panchromic absorption extending as far as 800 nm, making them of interest for solar-energy-harvesting applications.

Original languageEnglish
Pages (from-to)12560-12564
Number of pages5
JournalInorganic Chemistry
Volume51
Issue number22
DOIs
Publication statusPublished - 19 Nov 2012

Keywords

  • SENSITIZED SOLAR-CELLS
  • BIS(PHENYLIMINO)ACENAPHTHENE RHENIUM(I) COMPLEXES
  • PHOTOINDUCED HYDROGEN-PRODUCTION
  • CATALYTIC WATER REDUCTION
  • DENSITY-FUNCTIONAL THEORY
  • ALPHA-DIIMINE COMPLEXES
  • STRUCTURAL-CHARACTERIZATION
  • PHOTOPHYSICAL PROPERTIES
  • COPPER(II) COMPLEXES
  • PHOTOVOLTAIC CELLS

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