Palladium(II) driven self-assembly of a saturated quadruple-stranded metallo helicate

Debakanta Tripathy; Amlan Kumar Pal; Garry S. Hanan; Dillip Kumar Chand

doi:10.1039/C2DT30937H

Palladium(II) driven self-assembly of a saturated quadruple-stranded metallo helicate

Debakanta Tripathy, Amlan Kumar Pal, Garry S. Hanan, Dillip Kumar Chand

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Complexation of the bridging bidentate ligand N,N′-(pyridine-2,6-diyl)dinicotinamide, L with palladium(II) resulted in a single discrete M2L4 self-assembly, 1, in a quantitative manner. The entropically-controlled assembly of 1 resulted in a rare saturated, quadruple-stranded metallo-helicate, in which both the left-handed (M) and right-handed (P) helicates exist in the crystal structure.

Original language	English
Pages (from-to)	11273-11275
Journal	Dalton Transactions
Volume	41
Issue number	37
DOIs	https://doi.org/10.1039/C2DT30937H
Publication status	Published - 16 Aug 2012

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abstract = "Complexation of the bridging bidentate ligand N,N′-(pyridine-2,6-diyl)dinicotinamide, L with palladium(II) resulted in a single discrete M2L4 self-assembly, 1, in a quantitative manner. The entropically-controlled assembly of 1 resulted in a rare saturated, quadruple-stranded metallo-helicate, in which both the left-handed (M) and right-handed (P) helicates exist in the crystal structure.",

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AU - Tripathy, Debakanta

AU - Pal, Amlan Kumar

AU - Hanan, Garry S.

AU - Chand, Dillip Kumar

PY - 2012/8/16

Y1 - 2012/8/16

N2 - Complexation of the bridging bidentate ligand N,N′-(pyridine-2,6-diyl)dinicotinamide, L with palladium(II) resulted in a single discrete M2L4 self-assembly, 1, in a quantitative manner. The entropically-controlled assembly of 1 resulted in a rare saturated, quadruple-stranded metallo-helicate, in which both the left-handed (M) and right-handed (P) helicates exist in the crystal structure.

AB - Complexation of the bridging bidentate ligand N,N′-(pyridine-2,6-diyl)dinicotinamide, L with palladium(II) resulted in a single discrete M2L4 self-assembly, 1, in a quantitative manner. The entropically-controlled assembly of 1 resulted in a rare saturated, quadruple-stranded metallo-helicate, in which both the left-handed (M) and right-handed (P) helicates exist in the crystal structure.

UR - https://www.scopus.com/pages/publications/84872099329

U2 - 10.1039/C2DT30937H

DO - 10.1039/C2DT30937H

M3 - Article

SN - 1477-9226

VL - 41

SP - 11273

EP - 11275

JO - Dalton Transactions

JF - Dalton Transactions

IS - 37

ER -

Palladium(II) driven self-assembly of a saturated quadruple-stranded metallo helicate

Abstract

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