Palladium(II) driven self-assembly of a saturated quadruple-stranded metallo helicate

Debakanta Tripathy, Amlan Kumar Pal, Garry S. Hanan, Dillip Kumar Chand

Research output: Contribution to journalArticlepeer-review

43 Citations (Scopus)

Abstract

Complexation of the bridging bidentate ligand N,N′-(pyridine-2,6-diyl)dinicotinamide, L with palladium(II) resulted in a single discrete M2L4 self-assembly, 1, in a quantitative manner. The entropically-controlled assembly of 1 resulted in a rare saturated, quadruple-stranded metallo-helicate, in which both the left-handed (M) and right-handed (P) helicates exist in the crystal structure.
Original languageEnglish
Pages (from-to)11273-11275
JournalDalton Transactions
Volume41
Issue number37
DOIs
Publication statusPublished - 16 Aug 2012

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