Palladium complexes of new bulky fluorinated diphosphines give particularly active and regioselective catalysts for hydroxycarbonylation of styrene

Jamie J. R. Frew; Matthew L. Clarke; Ulrich Mayer; Hendrik Van Rensburg; Robert P. Tooze

doi:10.1039/b719012c

Palladium complexes of new bulky fluorinated diphosphines give particularly active and regioselective catalysts for hydroxycarbonylation of styrene

Jamie J. R. Frew, Matthew L. Clarke, Ulrich Mayer, Hendrik Van Rensburg, Robert P. Tooze

Research output: Contribution to journal › Article › peer-review

Abstract

Some new bulky fluorinated diphosphines have been prepared and converted to palladium dichloride complexes that have been found to give increased regioselectivity and activity over other Pd-diphosphine systems when used as catalysts for hydroxycarbonylation of styrene.

Original language	English
Pages (from-to)	1976-1978
Number of pages	3
Journal	Dalton Transactions
Issue number	15
DOIs	https://doi.org/10.1039/b719012c
Publication status	Published - 21 Apr 2008

Keywords

2-ARYLPROPIONIC ACIDS
UNSATURATED ESTERS
INTERNAL ALKENES
VINYL AROMATICS
LINEAR ESTERS
HYDROFORMYLATION
CARBONYLATION
LIGANDS
METHOXYCARBONYLATION
HYDROESTERIFICATION

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title = "Palladium complexes of new bulky fluorinated diphosphines give particularly active and regioselective catalysts for hydroxycarbonylation of styrene",

abstract = "Some new bulky fluorinated diphosphines have been prepared and converted to palladium dichloride complexes that have been found to give increased regioselectivity and activity over other Pd-diphosphine systems when used as catalysts for hydroxycarbonylation of styrene.",

keywords = "2-ARYLPROPIONIC ACIDS, UNSATURATED ESTERS, INTERNAL ALKENES, VINYL AROMATICS, LINEAR ESTERS, HYDROFORMYLATION, CARBONYLATION, LIGANDS, METHOXYCARBONYLATION, HYDROESTERIFICATION",

author = "Frew, {Jamie J. R.} and Clarke, {Matthew L.} and Ulrich Mayer and {Van Rensburg}, Hendrik and Tooze, {Robert P.}",

year = "2008",

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day = "21",

doi = "10.1039/b719012c",

language = "English",

pages = "1976--1978",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "ROYAL SOC CHEMISTRY",

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T1 - Palladium complexes of new bulky fluorinated diphosphines give particularly active and regioselective catalysts for hydroxycarbonylation of styrene

AU - Frew, Jamie J. R.

AU - Clarke, Matthew L.

AU - Mayer, Ulrich

AU - Van Rensburg, Hendrik

AU - Tooze, Robert P.

PY - 2008/4/21

Y1 - 2008/4/21

N2 - Some new bulky fluorinated diphosphines have been prepared and converted to palladium dichloride complexes that have been found to give increased regioselectivity and activity over other Pd-diphosphine systems when used as catalysts for hydroxycarbonylation of styrene.

AB - Some new bulky fluorinated diphosphines have been prepared and converted to palladium dichloride complexes that have been found to give increased regioselectivity and activity over other Pd-diphosphine systems when used as catalysts for hydroxycarbonylation of styrene.

KW - 2-ARYLPROPIONIC ACIDS

KW - UNSATURATED ESTERS

KW - INTERNAL ALKENES

KW - VINYL AROMATICS

KW - LINEAR ESTERS

KW - HYDROFORMYLATION

KW - CARBONYLATION

KW - LIGANDS

KW - METHOXYCARBONYLATION

KW - HYDROESTERIFICATION

UR - http://www.scopus.com/inward/record.url?scp=41549111599&partnerID=8YFLogxK

U2 - 10.1039/b719012c

DO - 10.1039/b719012c

M3 - Article

SN - 1477-9226

SP - 1976

EP - 1978

JO - Dalton Transactions

JF - Dalton Transactions

IS - 15

ER -

Palladium complexes of new bulky fluorinated diphosphines give particularly active and regioselective catalysts for hydroxycarbonylation of styrene

Abstract

Keywords

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