Palladium complexes of new bulky fluorinated diphosphines give particularly active and regioselective catalysts for hydroxycarbonylation of styrene

Jamie J. R. Frew, Matthew L. Clarke, Ulrich Mayer, Hendrik Van Rensburg, Robert P. Tooze

Research output: Contribution to journalArticlepeer-review

18 Citations (Scopus)

Abstract

Some new bulky fluorinated diphosphines have been prepared and converted to palladium dichloride complexes that have been found to give increased regioselectivity and activity over other Pd-diphosphine systems when used as catalysts for hydroxycarbonylation of styrene.

Original languageEnglish
Pages (from-to)1976-1978
Number of pages3
JournalDalton Transactions
Issue number15
DOIs
Publication statusPublished - 21 Apr 2008

Keywords

  • 2-ARYLPROPIONIC ACIDS
  • UNSATURATED ESTERS
  • INTERNAL ALKENES
  • VINYL AROMATICS
  • LINEAR ESTERS
  • HYDROFORMYLATION
  • CARBONYLATION
  • LIGANDS
  • METHOXYCARBONYLATION
  • HYDROESTERIFICATION

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