P-N-S/Se Containing Metallacycles

John Derek Woollins

doi:10.1039/dt9960002893

P-N-S/Se Containing Metallacycles

John Derek Woollins

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Abstract

Metal complexes containing only Group 15 and 16 elements in the chelate rings are studied extensively in M-S-N chemistry. Recently M-E-P-N type systems are starting to reveal interesting conformational and structural properties;. examples of syntheses and structures are provided. The cover shows the crystal structures (DIAMOND drawings) of [M{(Pr2P)-P-1(S)NP(S)Pr-2(1)}(2)] (M = Pd or Pt) illustrating the surprising conformational change effected by replacing a palladium by a platinum centre.

Original language	English
Pages (from-to)	2893-2901
Number of pages	10
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	14
DOIs	https://doi.org/10.1039/dt9960002893
Publication status	Published - 1996

Keywords

MOLECULAR-STRUCTURE
CRYSTAL-STRUCTURE
TETRAPHENYL IMIDODIPHOSPHATE
DERIVATIVES
SULFUR
LIGANDS
ACID
BIS(DIPHENYLPHOSPHINO)AMINE
REACTIVITY
COMPLEXES

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@article{26394d0b40564e3da6fe13cd6f01dad1,

title = "P-N-S/Se Containing Metallacycles",

abstract = "Metal complexes containing only Group 15 and 16 elements in the chelate rings are studied extensively in M-S-N chemistry. Recently M-E-P-N type systems are starting to reveal interesting conformational and structural properties;. examples of syntheses and structures are provided. The cover shows the crystal structures (DIAMOND drawings) of [M\{(Pr2P)-P-1(S)NP(S)Pr-2(1)\}(2)] (M = Pd or Pt) illustrating the surprising conformational change effected by replacing a palladium by a platinum centre.",

keywords = "MOLECULAR-STRUCTURE, CRYSTAL-STRUCTURE, TETRAPHENYL IMIDODIPHOSPHATE, DERIVATIVES, SULFUR, LIGANDS, ACID, BIS(DIPHENYLPHOSPHINO)AMINE, REACTIVITY, COMPLEXES",

author = "Woollins, \{John Derek\}",

year = "1996",

doi = "10.1039/dt9960002893",

language = "English",

pages = "2893--2901",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

number = "14",

}

TY - JOUR

T1 - P-N-S/Se Containing Metallacycles

AU - Woollins, John Derek

PY - 1996

Y1 - 1996

N2 - Metal complexes containing only Group 15 and 16 elements in the chelate rings are studied extensively in M-S-N chemistry. Recently M-E-P-N type systems are starting to reveal interesting conformational and structural properties;. examples of syntheses and structures are provided. The cover shows the crystal structures (DIAMOND drawings) of [M{(Pr2P)-P-1(S)NP(S)Pr-2(1)}(2)] (M = Pd or Pt) illustrating the surprising conformational change effected by replacing a palladium by a platinum centre.

AB - Metal complexes containing only Group 15 and 16 elements in the chelate rings are studied extensively in M-S-N chemistry. Recently M-E-P-N type systems are starting to reveal interesting conformational and structural properties;. examples of syntheses and structures are provided. The cover shows the crystal structures (DIAMOND drawings) of [M{(Pr2P)-P-1(S)NP(S)Pr-2(1)}(2)] (M = Pd or Pt) illustrating the surprising conformational change effected by replacing a palladium by a platinum centre.

KW - MOLECULAR-STRUCTURE

KW - CRYSTAL-STRUCTURE

KW - TETRAPHENYL IMIDODIPHOSPHATE

KW - DERIVATIVES

KW - SULFUR

KW - LIGANDS

KW - ACID

KW - BIS(DIPHENYLPHOSPHINO)AMINE

KW - REACTIVITY

KW - COMPLEXES

UR - https://www.scopus.com/pages/publications/33748498902

U2 - 10.1039/dt9960002893

DO - 10.1039/dt9960002893

M3 - Article

SN - 0300-9246

SP - 2893

EP - 2901

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 14

ER -

P-N-S/Se Containing Metallacycles

Abstract

Keywords

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