P-N-S/Se Containing Metallacycles

John Derek Woollins

Research output: Contribution to journalArticlepeer-review

125 Citations (Scopus)

Abstract

Metal complexes containing only Group 15 and 16 elements in the chelate rings are studied extensively in M-S-N chemistry. Recently M-E-P-N type systems are starting to reveal interesting conformational and structural properties;. examples of syntheses and structures are provided. The cover shows the crystal structures (DIAMOND drawings) of [M{(Pr2P)-P-1(S)NP(S)Pr-2(1)}(2)] (M = Pd or Pt) illustrating the surprising conformational change effected by replacing a palladium by a platinum centre.

Original languageEnglish
Pages (from-to)2893-2901
Number of pages10
JournalJournal of the Chemical Society, Dalton Transactions
Issue number14
DOIs
Publication statusPublished - 1996

Keywords

  • MOLECULAR-STRUCTURE
  • CRYSTAL-STRUCTURE
  • TETRAPHENYL IMIDODIPHOSPHATE
  • DERIVATIVES
  • SULFUR
  • LIGANDS
  • ACID
  • BIS(DIPHENYLPHOSPHINO)AMINE
  • REACTIVITY
  • COMPLEXES

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