P-N bond formation as a route to highly electron rich phosphine ligands

Matthew Lee Clarke; David John Cole-Hamilton; Alexandra Martha Zoya Slawin; John Derek Woollins

doi:10.1039/B004893N

P-N bond formation as a route to highly electron rich phosphine ligands

Matthew Lee Clarke, David John Cole-Hamilton, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

Phosphines containing two N-bound pyrrolidine groups and one alkyl or aryl group are unusually electron rich sigma-donor ligands when compared to either tris(N-pyrrolidinyl)phosphine or trialkyl- and triaryl-phosphines.

Original language	English
Pages (from-to)	2065-2066
Number of pages	2
Journal	Chemical Communications
Issue number	20
DOIs	https://doi.org/10.1039/B004893N
Publication status	Published - 2000

Keywords

PHOSPHORUS-NITROGEN BOND
CRYSTAL-STRUCTURE
ARYL CHLORIDES
CATALYSTS
TRIS(MORPHOLINO)PHOSPHINE
TRIS(PIPERIDINO)PHOSPHINE
COMPLEXES

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title = "P-N bond formation as a route to highly electron rich phosphine ligands",

abstract = "Phosphines containing two N-bound pyrrolidine groups and one alkyl or aryl group are unusually electron rich sigma-donor ligands when compared to either tris(N-pyrrolidinyl)phosphine or trialkyl- and triaryl-phosphines.",

keywords = "PHOSPHORUS-NITROGEN BOND, CRYSTAL-STRUCTURE, ARYL CHLORIDES, CATALYSTS, TRIS(MORPHOLINO)PHOSPHINE, TRIS(PIPERIDINO)PHOSPHINE, COMPLEXES",

author = "Clarke, {Matthew Lee} and Cole-Hamilton, {David John} and Slawin, {Alexandra Martha Zoya} and Woollins, {John Derek}",

year = "2000",

doi = "10.1039/B004893N",

language = "English",

pages = "2065--2066",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "20",

}

TY - JOUR

T1 - P-N bond formation as a route to highly electron rich phosphine ligands

AU - Clarke, Matthew Lee

AU - Cole-Hamilton, David John

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, John Derek

PY - 2000

Y1 - 2000

N2 - Phosphines containing two N-bound pyrrolidine groups and one alkyl or aryl group are unusually electron rich sigma-donor ligands when compared to either tris(N-pyrrolidinyl)phosphine or trialkyl- and triaryl-phosphines.

AB - Phosphines containing two N-bound pyrrolidine groups and one alkyl or aryl group are unusually electron rich sigma-donor ligands when compared to either tris(N-pyrrolidinyl)phosphine or trialkyl- and triaryl-phosphines.

KW - PHOSPHORUS-NITROGEN BOND

KW - CRYSTAL-STRUCTURE

KW - ARYL CHLORIDES

KW - CATALYSTS

KW - TRIS(MORPHOLINO)PHOSPHINE

KW - TRIS(PIPERIDINO)PHOSPHINE

KW - COMPLEXES

UR - http://www.scopus.com/inward/record.url?scp=0034699964&partnerID=8YFLogxK

U2 - 10.1039/B004893N

DO - 10.1039/B004893N

M3 - Article

SN - 1359-7345

SP - 2065

EP - 2066

JO - Chemical Communications

JF - Chemical Communications

IS - 20

ER -

P-N bond formation as a route to highly electron rich phosphine ligands

Abstract

Keywords

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