Oxygen redox activity through a reductive coupling mechanism in the P3-type nickel-doped sodium manganese oxide

Eun Jeong Kim, Le Anh Ma, Laurent C Duda, David M Pickup, Alan V Chadwick, Reza Younesi, John T. S. Irvine, Robert Armstrong*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

55 Citations (Scopus)
4 Downloads (Pure)

Abstract

Increasing dependence on rechargeable batteries for energy storage calls for the improvement of energy density of batteries. Toward this goal, introduction of positive electrode materials with high voltage and/or high capacity is in high demand. The use of oxygen chemistry in lithium and sodium layered oxides has been of interest to achieve high capacity. Nevertheless, a complete understanding of oxygen-based redox processes remains elusive especially in sodium ion batteries. Herein, a novel P3-type Na0.67Ni0.2Mn0.8O2, synthesized at low temperature, exhibits oxygen redox activity in high potentials. Characterization using a range of spectroscopic techniques reveals the anionic redox activity is stabilized by the reduction of Ni, because of the strong Ni 3d–O 2p hybridization states created during charge. This observation suggests that different route of oxygen redox processes occur in P3 structure materials, which can lead to the exploration of oxygen redox chemistry for further development in rechargeable batteries.
Original languageEnglish
JournalACS Applied Energy Materials
VolumeEarly View
Early online date6 Jan 2020
DOIs
Publication statusE-pub ahead of print - 6 Jan 2020

Keywords

  • Sodium ion batteries
  • Layered oxides
  • Anion redox
  • P3 structure
  • Reductive coupling mechanism
  • Resonant inelastic X-ray scattering

Fingerprint

Dive into the research topics of 'Oxygen redox activity through a reductive coupling mechanism in the P3-type nickel-doped sodium manganese oxide'. Together they form a unique fingerprint.

Cite this