OXIDATION CATALYSTS PRODUCED BY CATALYTIC-OXIDATION - PREPARATION, REACTIVITY AND X-RAY CRYSTAL-STRUCTURES OF [WO(O-2)(2)(PYO)(2)] AND [MOO(O-2)(2)(PYO)(2)]

W P GRIFFITH, A M Z SLAWIN, K M THOMPSON, D J WILLIAMS

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32 Citations (Scopus)

Abstract

The X-ray crystal structures of the pentagonal bipyramidal title complexes are reported (pyO = pyridine-N-oxide); these complexes were made by the oxidation by H2O2 of pyridine, catalysed by [MoO4](2-) and [WO4](2-), and are themselves catalysts for oxidations by H2O2.

Original languageEnglish
Pages (from-to)569-570
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number5
Publication statusPublished - 7 Mar 1994

Keywords

  • PEROXO COMPLEXES
  • AQUEOUS-SOLUTION

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