Oxamate and Chloranilate Bridges in Polymeric Networks

P Veltsistas; C Papadimitriou; Y Arabatzis; Alexandra Martha Zoya Slawin; John Derek Woollins

Oxamate and Chloranilate Bridges in Polymeric Networks

P Veltsistas, C Papadimitriou, Y Arabatzis, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Other contribution

Abstract

Oxamic acid acts as a bridging ligand with lanthanide ions to form, for example 9-coordinate Ho(III) systems in which the holmium centres are linked into sheets via H-bonds. Nd(III) also forms 9-coordinate complexes with oxamate but an alternative packing motif is observed. Multidentate ligands such as chloroanilate can also induce interesting networks. Thus with sodium and phenanthroline a complex which contains 7-coordinate sodium atoms linked together to form infinite double chains is observed.

Original language	English
Volume	125
Publication status	Published - 1997

Keywords

supramolecular structures
holmium
neodymium, sodium, oxamate
chloroanilate

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title = "Oxamate and Chloranilate Bridges in Polymeric Networks",

abstract = "Oxamic acid acts as a bridging ligand with lanthanide ions to form, for example 9-coordinate Ho(III) systems in which the holmium centres are linked into sheets via H-bonds. Nd(III) also forms 9-coordinate complexes with oxamate but an alternative packing motif is observed. Multidentate ligands such as chloroanilate can also induce interesting networks. Thus with sodium and phenanthroline a complex which contains 7-coordinate sodium atoms linked together to form infinite double chains is observed.",

keywords = "supramolecular structures, holmium, neodymium, sodium, oxamate, chloroanilate",

author = "P Veltsistas and C Papadimitriou and Y Arabatzis and Slawin, {Alexandra Martha Zoya} and Woollins, {John Derek}",

note = "Phosphorus, Sulfur, Silicon",

year = "1997",

language = "English",

volume = "125",

type = "Other",

}

TY - GEN

T1 - Oxamate and Chloranilate Bridges in Polymeric Networks

AU - Veltsistas, P

AU - Papadimitriou, C

AU - Arabatzis, Y

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, John Derek

N1 - Phosphorus, Sulfur, Silicon

PY - 1997

Y1 - 1997

N2 - Oxamic acid acts as a bridging ligand with lanthanide ions to form, for example 9-coordinate Ho(III) systems in which the holmium centres are linked into sheets via H-bonds. Nd(III) also forms 9-coordinate complexes with oxamate but an alternative packing motif is observed. Multidentate ligands such as chloroanilate can also induce interesting networks. Thus with sodium and phenanthroline a complex which contains 7-coordinate sodium atoms linked together to form infinite double chains is observed.

AB - Oxamic acid acts as a bridging ligand with lanthanide ions to form, for example 9-coordinate Ho(III) systems in which the holmium centres are linked into sheets via H-bonds. Nd(III) also forms 9-coordinate complexes with oxamate but an alternative packing motif is observed. Multidentate ligands such as chloroanilate can also induce interesting networks. Thus with sodium and phenanthroline a complex which contains 7-coordinate sodium atoms linked together to form infinite double chains is observed.

KW - supramolecular structures

KW - holmium

KW - neodymium, sodium, oxamate

KW - chloroanilate

M3 - Other contribution

VL - 125

ER -

Oxamate and Chloranilate Bridges in Polymeric Networks

Abstract

Keywords

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