Orthometalation of functionalized phosphinoamines with late transition metal complexes

K G Gaw, A M Z Slawin, M B Smith

Research output: Contribution to journalArticlepeer-review

28 Citations (Scopus)

Abstract

The neutral metal complexes cis-[Pt(CH3)(2)-{o-Ph2PN(H)C6H4C(O)CH3-P}(2)] and [RhCl2(Cp*){o-Ph-2-PN(H)C6H4C(O)Ph-P}] are excellent precursors for new five-membered M-P-N-C-C metallacycles via sigma(C-sp(2)-H) bond activation. The synthesis and characterization including the molecular structures of cis-[Pt{o-Ph2PN(H)C6H3C(O)CH3-P,C}(2)]. OEt2 and [RhCl(Cp*) {o-Ph2PN(H)C6H3C(O)Ph-P,C}]. 0.5CHCl(3) are reported.

Original languageEnglish
Pages (from-to)3255-3257
Number of pages3
JournalOrganometallics
Volume18
Issue number17
DOIs
Publication statusPublished - 16 Aug 1999

Keywords

  • COUPLING REACTIONS
  • CATALYSTS
  • PALLADACYCLES
  • EFFICIENT
  • ACETATE
  • LIGAND

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