Orthometalation of functionalized phosphinoamines with late transition metal complexes

K G  Gaw; A M Z  Slawin; M B  Smith

doi:10.1021/om990363b

Orthometalation of functionalized phosphinoamines with late transition metal complexes

K G Gaw, A M Z Slawin, M B Smith

Research output: Contribution to journal › Article › peer-review

Abstract

The neutral metal complexes cis-[Pt(CH3)(2)-{o-Ph2PN(H)C6H4C(O)CH3-P}(2)] and [RhCl2(Cp*){o-Ph-2-PN(H)C6H4C(O)Ph-P}] are excellent precursors for new five-membered M-P-N-C-C metallacycles via sigma(C-sp(2)-H) bond activation. The synthesis and characterization including the molecular structures of cis-[Pt{o-Ph2PN(H)C6H3C(O)CH3-P,C}(2)]. OEt2 and [RhCl(Cp*) {o-Ph2PN(H)C6H3C(O)Ph-P,C}]. 0.5CHCl(3) are reported.

Original language	English
Pages (from-to)	3255-3257
Number of pages	3
Journal	Organometallics
Volume	18
Issue number	17
DOIs	https://doi.org/10.1021/om990363b
Publication status	Published - 16 Aug 1999

Keywords

COUPLING REACTIONS
CATALYSTS
PALLADACYCLES
EFFICIENT
ACETATE
LIGAND

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10.1021/om990363b

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title = "Orthometalation of functionalized phosphinoamines with late transition metal complexes",

abstract = "The neutral metal complexes cis-[Pt(CH3)(2)-{o-Ph2PN(H)C6H4C(O)CH3-P}(2)] and [RhCl2(Cp*){o-Ph-2-PN(H)C6H4C(O)Ph-P}] are excellent precursors for new five-membered M-P-N-C-C metallacycles via sigma(C-sp(2)-H) bond activation. The synthesis and characterization including the molecular structures of cis-[Pt{o-Ph2PN(H)C6H3C(O)CH3-P,C}(2)]. OEt2 and [RhCl(Cp*) {o-Ph2PN(H)C6H3C(O)Ph-P,C}]. 0.5CHCl(3) are reported.",

keywords = "COUPLING REACTIONS, CATALYSTS, PALLADACYCLES, EFFICIENT, ACETATE, LIGAND",

author = "Gaw, {K G} and Slawin, {A M Z} and Smith, {M B}",

year = "1999",

month = aug,

day = "16",

doi = "10.1021/om990363b",

language = "English",

volume = "18",

pages = "3255--3257",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society (ACS)",

number = "17",

}

TY - JOUR

T1 - Orthometalation of functionalized phosphinoamines with late transition metal complexes

AU - Gaw, K G

AU - Slawin, A M Z

AU - Smith, M B

PY - 1999/8/16

Y1 - 1999/8/16

N2 - The neutral metal complexes cis-[Pt(CH3)(2)-{o-Ph2PN(H)C6H4C(O)CH3-P}(2)] and [RhCl2(Cp*){o-Ph-2-PN(H)C6H4C(O)Ph-P}] are excellent precursors for new five-membered M-P-N-C-C metallacycles via sigma(C-sp(2)-H) bond activation. The synthesis and characterization including the molecular structures of cis-[Pt{o-Ph2PN(H)C6H3C(O)CH3-P,C}(2)]. OEt2 and [RhCl(Cp*) {o-Ph2PN(H)C6H3C(O)Ph-P,C}]. 0.5CHCl(3) are reported.

AB - The neutral metal complexes cis-[Pt(CH3)(2)-{o-Ph2PN(H)C6H4C(O)CH3-P}(2)] and [RhCl2(Cp*){o-Ph-2-PN(H)C6H4C(O)Ph-P}] are excellent precursors for new five-membered M-P-N-C-C metallacycles via sigma(C-sp(2)-H) bond activation. The synthesis and characterization including the molecular structures of cis-[Pt{o-Ph2PN(H)C6H3C(O)CH3-P,C}(2)]. OEt2 and [RhCl(Cp*) {o-Ph2PN(H)C6H3C(O)Ph-P,C}]. 0.5CHCl(3) are reported.

KW - COUPLING REACTIONS

KW - CATALYSTS

KW - PALLADACYCLES

KW - EFFICIENT

KW - ACETATE

KW - LIGAND

U2 - 10.1021/om990363b

DO - 10.1021/om990363b

M3 - Article

SN - 0276-7333

VL - 18

SP - 3255

EP - 3257

JO - Organometallics

JF - Organometallics

IS - 17

ER -

Orthometalation of functionalized phosphinoamines with late transition metal complexes

Abstract

Keywords

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