ORGANOTIN-DMIT COMPLEXES - CRYSTAL-STRUCTURE OF [BU4N][ME2SNCL(DMIT)]

SMSV DOIDGEHARRISON; RA HOWIE; JTS IRVINE; G SPENCER; JL WARDELL; John Thomas Sirr Irvine

ORGANOTIN-DMIT COMPLEXES - CRYSTAL-STRUCTURE OF [BU4N][ME2SNCL(DMIT)]

SMSV DOIDGEHARRISON, RA HOWIE, JTS IRVINE, G SPENCER, JL WARDELL, John Thomas Sirr Irvine

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Various organotin-DMIT complexes have been prepared from organotin halides and [Bu4N]2[Ni(DMIT)2] (H2-DMIT = 4,5-dimercapto-1,3-dithiole-2-thione). The crystal structure of [Bu4N][Me2ClSn(DMIT)] (V, R = Me) is reported: the compounds contains a trigonal bipyramidal tin atom in the anion.

Original language	English
Pages (from-to)	C5-C8
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	414
Issue number	1
Publication status	Published - 13 Aug 1991

Keywords

METAL
ELECTRONIC-STRUCTURES
SUPERCONDUCTOR
PHASE-TRANSITION
MOLECULAR CONDUCTOR
NI(DMIT)2
X-RAY
RESISTIVITY
<(CH3)4N><NI(DMIT)2>2
1,3-DITHIOLE-2-THIONE-4,5-DITHIOLATE DMIT

Cite this

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title = "ORGANOTIN-DMIT COMPLEXES - CRYSTAL-STRUCTURE OF [BU4N][ME2SNCL(DMIT)]",

abstract = "Various organotin-DMIT complexes have been prepared from organotin halides and [Bu4N]2[Ni(DMIT)2] (H2-DMIT = 4,5-dimercapto-1,3-dithiole-2-thione). The crystal structure of [Bu4N][Me2ClSn(DMIT)] (V, R = Me) is reported: the compounds contains a trigonal bipyramidal tin atom in the anion.",

keywords = "METAL, ELECTRONIC-STRUCTURES, SUPERCONDUCTOR, PHASE-TRANSITION, MOLECULAR CONDUCTOR, NI(DMIT)2, X-RAY, RESISTIVITY, <(CH3)4N><NI(DMIT)2>2, 1,3-DITHIOLE-2-THIONE-4,5-DITHIOLATE DMIT",

author = "SMSV DOIDGEHARRISON and RA HOWIE and JTS IRVINE and G SPENCER and JL WARDELL and Irvine, {John Thomas Sirr}",

year = "1991",

month = aug,

day = "13",

language = "English",

volume = "414",

pages = "C5--C8",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

number = "1",

}

TY - JOUR

T1 - ORGANOTIN-DMIT COMPLEXES - CRYSTAL-STRUCTURE OF [BU4N][ME2SNCL(DMIT)]

AU - DOIDGEHARRISON, SMSV

AU - HOWIE, RA

AU - IRVINE, JTS

AU - SPENCER, G

AU - WARDELL, JL

AU - Irvine, John Thomas Sirr

PY - 1991/8/13

Y1 - 1991/8/13

N2 - Various organotin-DMIT complexes have been prepared from organotin halides and [Bu4N]2[Ni(DMIT)2] (H2-DMIT = 4,5-dimercapto-1,3-dithiole-2-thione). The crystal structure of [Bu4N][Me2ClSn(DMIT)] (V, R = Me) is reported: the compounds contains a trigonal bipyramidal tin atom in the anion.

AB - Various organotin-DMIT complexes have been prepared from organotin halides and [Bu4N]2[Ni(DMIT)2] (H2-DMIT = 4,5-dimercapto-1,3-dithiole-2-thione). The crystal structure of [Bu4N][Me2ClSn(DMIT)] (V, R = Me) is reported: the compounds contains a trigonal bipyramidal tin atom in the anion.

KW - METAL

KW - ELECTRONIC-STRUCTURES

KW - SUPERCONDUCTOR

KW - PHASE-TRANSITION

KW - MOLECULAR CONDUCTOR

KW - NI(DMIT)2

KW - X-RAY

KW - RESISTIVITY

KW - <(CH3)4N><NI(DMIT)2>2

KW - 1,3-DITHIOLE-2-THIONE-4,5-DITHIOLATE DMIT

M3 - Article

SN - 0022-328X

VL - 414

SP - C5-C8

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

ORGANOTIN-DMIT COMPLEXES - CRYSTAL-STRUCTURE OF [BU4N][ME2SNCL(DMIT)]

Abstract

Keywords

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