Organic chemistry on surfaces: direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs)

Malgorzata Adamkiewicz, David O'Hagan, Georg Hähner

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

C11-Vinyl-terminated self-assembled monolayers (SAMs) on silica surfaces are successfully modified in C–C bond forming reactions with dihalocarbenes to generate SAMs, terminated with dihalo- (fluoro, chloro, bromo) cyclopropane motifs with about 30% surface coverage.
Original languageEnglish
Pages (from-to)2897–2902
Number of pages6
JournalBeilstein Journal of Organic Chemistry
Volume10
Early online date5 Dec 2014
DOIs
Publication statusPublished - 5 Dec 2014

Keywords

  • difluoro-
  • dichloro-
  • dibromomethylenecyclopropanes
  • dihalocarbenes
  • Self-assembled monolayers
  • surface coating

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