Operando Spectroscopy in Catalytic Carbonylation Reactions

Olivier Diebolt, Piet W. N. M. van Leeuwen, Paul C. J. Kamer*

*Corresponding author for this work

Research output: Contribution to journalReview articlepeer-review

54 Citations (Scopus)

Abstract

Over the years, in situ spectroscopic studies have contributed largely to an in-depth mechanistic understanding of many homogeneously catalyzed reactions. This review discusses the application of operando spectroscopy such as high pressure infrared and NMR to obtain in-depth mechanistic understanding of transition metal catalyzed carbonylation reactions. Several catalytic reactions of industrial relevance are discussed including rhodium catalyzed hydroformylation, palladium catalyzed alkoxycarbonylation, and copolymerization of CO and alkenes. Also, mechanistic studies of tandem reactions such as rhodium catalyzed hydroaminomethylation and hydroformylation-hydrogenation are included. In addition, the effects of alternative media such as supercritical CO2 and ionic liquids are discussed.

Original languageEnglish
Pages (from-to)2357-2370
Number of pages14
JournalACS Catalysis
Volume2
Issue number11
DOIs
Publication statusPublished - Nov 2012

Keywords

  • SUPERCRITICAL CARBON-DIOXIDE
  • carbonylation
  • PHOSPHINE-PHOSPHITE LIGANDS
  • PARAHYDROGEN-INDUCED POLARIZATION
  • TRANSITION-METAL CATALYSTS
  • BITE-ANGLE DIPHOSPHINES
  • PREPARE BIDENTATE LIGANDS
  • HP-IR
  • HIGHLY SELECTIVE HYDROAMINOMETHYLATION
  • TANDEM REACTION SEQUENCES
  • in situ spectroscopy
  • HP-NMR
  • homogeneous catalysis
  • ENTROPY MINIMIZATION BTEM
  • operando spectroscopy
  • RHODIUM TRIALKYLPHOSPHINE COMPLEXES
  • hydroformylation

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