One ponytail will do: New partially fluorinated phosphine ligands with applications in fluorous biphasic solvent systems

Matthew L Clarke

One ponytail will do: New partially fluorinated phosphine ligands with applications in fluorous biphasic solvent systems

Research output: Contribution to journal › Article › peer-review

Abstract

The first 'fluorous soluble' metal complexes derived from a phosphino-amine are reported. Attaching a single perfluorinated 'ponytail' to the (C6F5)(2)P fragment is sufficient to give rhodium complexes that show high partition co-efficients between perfluoromethylcycloltexane and toluene. (C) 2002 Elsevier Science B.V. All rights reserved.

Original language	English
Pages (from-to)	65
Number of pages	65
Journal	Journal of Organometallic Chemistry
Volume	665
Publication status	Published - 3 Jan 2003

Keywords

biphasic catalysis
rhodium complexes
phosphines
fluorine chemistry
CATALYZED HYDROFORMYLATION
CRYSTAL-STRUCTURES
COMPLEXES
SEPARATION
HYDROGENATION
LIGANDS

Cite this

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title = "One ponytail will do: New partially fluorinated phosphine ligands with applications in fluorous biphasic solvent systems",

abstract = "The first 'fluorous soluble' metal complexes derived from a phosphino-amine are reported. Attaching a single perfluorinated 'ponytail' to the (C6F5)(2)P fragment is sufficient to give rhodium complexes that show high partition co-efficients between perfluoromethylcycloltexane and toluene. (C) 2002 Elsevier Science B.V. All rights reserved.",

keywords = "biphasic catalysis, rhodium complexes, phosphines, fluorine chemistry, CATALYZED HYDROFORMYLATION, CRYSTAL-STRUCTURES, COMPLEXES, SEPARATION, HYDROGENATION, LIGANDS",

author = "Clarke, \{Matthew L\}",

year = "2003",

month = jan,

day = "3",

language = "English",

volume = "665",

pages = "65",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

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TY - JOUR

T1 - One ponytail will do: New partially fluorinated phosphine ligands with applications in fluorous biphasic solvent systems

AU - Clarke, Matthew L

PY - 2003/1/3

Y1 - 2003/1/3

N2 - The first 'fluorous soluble' metal complexes derived from a phosphino-amine are reported. Attaching a single perfluorinated 'ponytail' to the (C6F5)(2)P fragment is sufficient to give rhodium complexes that show high partition co-efficients between perfluoromethylcycloltexane and toluene. (C) 2002 Elsevier Science B.V. All rights reserved.

AB - The first 'fluorous soluble' metal complexes derived from a phosphino-amine are reported. Attaching a single perfluorinated 'ponytail' to the (C6F5)(2)P fragment is sufficient to give rhodium complexes that show high partition co-efficients between perfluoromethylcycloltexane and toluene. (C) 2002 Elsevier Science B.V. All rights reserved.

KW - biphasic catalysis

KW - rhodium complexes

KW - phosphines

KW - fluorine chemistry

KW - CATALYZED HYDROFORMYLATION

KW - CRYSTAL-STRUCTURES

KW - COMPLEXES

KW - SEPARATION

KW - HYDROGENATION

KW - LIGANDS

UR - https://www.scopus.com/pages/publications/0037414981

M3 - Article

SN - 0022-328X

VL - 665

SP - 65

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

One ponytail will do: New partially fluorinated phosphine ligands with applications in fluorous biphasic solvent systems

Abstract

Keywords

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