One ponytail will do: New partially fluorinated phosphine ligands with applications in fluorous biphasic solvent systems

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Abstract

The first 'fluorous soluble' metal complexes derived from a phosphino-amine are reported. Attaching a single perfluorinated 'ponytail' to the (C6F5)(2)P fragment is sufficient to give rhodium complexes that show high partition co-efficients between perfluoromethylcycloltexane and toluene. (C) 2002 Elsevier Science B.V. All rights reserved.

Original languageEnglish
Pages (from-to)65
Number of pages65
JournalJournal of Organometallic Chemistry
Volume665
Publication statusPublished - 3 Jan 2003

Keywords

  • biphasic catalysis
  • rhodium complexes
  • phosphines
  • fluorine chemistry
  • CATALYZED HYDROFORMYLATION
  • CRYSTAL-STRUCTURES
  • COMPLEXES
  • SEPARATION
  • HYDROGENATION
  • LIGANDS

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