On the NH Effect in Ruthenium-Catalysed Hydrogenation of Ketones: Rational Design of Phosphine-Amino-Alcohol Ligands for Asymmetric Hydrogenation of Ketones

Scott David Phillips; José Antonio Fuentes García; Matt  Clarke

doi:10.1002/chem.201000790

On the NH Effect in Ruthenium-Catalysed Hydrogenation of Ketones: Rational Design of Phosphine-Amino-Alcohol Ligands for Asymmetric Hydrogenation of Ketones

Scott David Phillips, José Antonio Fuentes García, Matt Clarke

Research output: Contribution to journal › Article › peer-review

56 Citations (Scopus)

Original language	English
Pages (from-to)	8002-8005
Number of pages	4
Journal	Chemistry - A European Journal
Volume	16
Issue number	27
Early online date	25 Jun 2010
DOIs	https://doi.org/10.1002/chem.201000790
Publication status	Published - 19 Jul 2010

Keywords

chirality
hydrogenation
kinetics
phosphines
tridentate ligands
HIGHLY ENANTIOSELECTIVE HYDROGENATION
AROMATIC KETONES
CARBONYL-COMPOUNDS
BINAP/1,2-DIAMINE-RUTHENIUM(II) COMPLEXES
STEREOSELECTIVE HYDROGENATION
BIFUNCTIONAL CATALYSIS
DIHYDRIDE COMPLEXES
HYDRIDE COMPLEXES
DONOR LIGANDS
MECHANISM

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10.1002/chem.201000790

Cite this

@article{67b0f72fb2104332b888f1594951dad5,

title = "On the NH Effect in Ruthenium-Catalysed Hydrogenation of Ketones: Rational Design of Phosphine-Amino-Alcohol Ligands for Asymmetric Hydrogenation of Ketones",

keywords = "chirality, hydrogenation, kinetics, phosphines, tridentate ligands, HIGHLY ENANTIOSELECTIVE HYDROGENATION, AROMATIC KETONES, CARBONYL-COMPOUNDS, BINAP/1,2-DIAMINE-RUTHENIUM(II) COMPLEXES, STEREOSELECTIVE HYDROGENATION, BIFUNCTIONAL CATALYSIS, DIHYDRIDE COMPLEXES, HYDRIDE COMPLEXES, DONOR LIGANDS, MECHANISM",

author = "Phillips, {Scott David} and {Fuentes Garc{\'i}a}, {Jos{\'e} Antonio} and Matt Clarke",

year = "2010",

month = jul,

day = "19",

doi = "10.1002/chem.201000790",

language = "English",

volume = "16",

pages = "8002--8005",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "John Wiley & Sons, Ltd",

number = "27",

}

On the NH Effect in Ruthenium-Catalysed Hydrogenation of Ketones: Rational Design of Phosphine-Amino-Alcohol Ligands for Asymmetric Hydrogenation of Ketones. / Phillips, Scott David; Fuentes García, José Antonio; Clarke, Matt .
In: Chemistry - A European Journal, Vol. 16, No. 27, 19.07.2010, p. 8002-8005.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - On the NH Effect in Ruthenium-Catalysed Hydrogenation of Ketones

T2 - Rational Design of Phosphine-Amino-Alcohol Ligands for Asymmetric Hydrogenation of Ketones

AU - Phillips, Scott David

AU - Fuentes García, José Antonio

AU - Clarke, Matt

PY - 2010/7/19

Y1 - 2010/7/19

KW - chirality

KW - hydrogenation

KW - kinetics

KW - phosphines

KW - tridentate ligands

KW - HIGHLY ENANTIOSELECTIVE HYDROGENATION

KW - AROMATIC KETONES

KW - CARBONYL-COMPOUNDS

KW - BINAP/1,2-DIAMINE-RUTHENIUM(II) COMPLEXES

KW - STEREOSELECTIVE HYDROGENATION

KW - BIFUNCTIONAL CATALYSIS

KW - DIHYDRIDE COMPLEXES

KW - HYDRIDE COMPLEXES

KW - DONOR LIGANDS

KW - MECHANISM

UR - http://www.scopus.com/inward/record.url?scp=77954720382&partnerID=8YFLogxK

U2 - 10.1002/chem.201000790

DO - 10.1002/chem.201000790

M3 - Article

SN - 0947-6539

VL - 16

SP - 8002

EP - 8005

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 27

ER -

On the NH Effect in Ruthenium-Catalysed Hydrogenation of Ketones: Rational Design of Phosphine-Amino-Alcohol Ligands for Asymmetric Hydrogenation of Ketones

Keywords

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EP/F030576 Ruthenium complexes: Ruthenium complexes of chiral tridentate ligands: a new class of catalyst for asymmetric ketone and imine hydrogenation

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On the NH Effect in Ruthenium-Catalysed Hydrogenation of Ketones: Rational Design of Phosphine-Amino-Alcohol Ligands for Asymmetric Hydrogenation of Ketones

Keywords

Access to Document

Other files and links

Projects

EP/F030576 Ruthenium complexes: Ruthenium complexes of chiral tridentate ligands: a new class of catalyst for asymmetric ketone and imine hydrogenation

Cite this