Olefin epoxidation by hydrogen peroxide catalysed by molybdenum complexes in ionic liquids and structural characterisation of the proposed intermediate dioxoperoxomolybdenum species

Matthew Herbert; Eleuterio Alvarez; David John Cole-Hamilton; Francisco Montilla; Agustin Galindo

doi:10.1039/c0cc00462f

Olefin epoxidation by hydrogen peroxide catalysed by molybdenum complexes in ionic liquids and structural characterisation of the proposed intermediate dioxoperoxomolybdenum species

Matthew Herbert, Eleuterio Alvarez, David John Cole-Hamilton, Francisco Montilla, Agustin Galindo

Research output: Contribution to journal › Article › peer-review

Abstract

The complex [Mo4O16(dmpz)(6)] (1) has been isolated as part of a study of oxodiperoxomolybdenum catalysed epoxidation of olefin substrates with hydrogen peroxide in ionic liquids. Notably, 1 is the first dioxoperoxomolybdenum species to be structurally characterised.

Original language	English
Pages (from-to)	5933-5935
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	32
DOIs	https://doi.org/10.1039/c0cc00462f
Publication status	Published - 2010

Keywords

DIPEROXO COMPLEXES
PEROXOMOLYBDENUM COMPLEXES
OXIDATION
MECHANISM
REACTIVITY
SULFOXIDES
SULFIDES
ALKENES
OXIDANT
OXYGEN

Access to Document

10.1039/c0cc00462f

Cite this

@article{df4a03f8853748d487fdc4ddb181ffc2,

title = "Olefin epoxidation by hydrogen peroxide catalysed by molybdenum complexes in ionic liquids and structural characterisation of the proposed intermediate dioxoperoxomolybdenum species",

abstract = "The complex [Mo4O16(dmpz)(6)] (1) has been isolated as part of a study of oxodiperoxomolybdenum catalysed epoxidation of olefin substrates with hydrogen peroxide in ionic liquids. Notably, 1 is the first dioxoperoxomolybdenum species to be structurally characterised.",

keywords = "DIPEROXO COMPLEXES, PEROXOMOLYBDENUM COMPLEXES, OXIDATION, MECHANISM, REACTIVITY, SULFOXIDES, SULFIDES, ALKENES, OXIDANT, OXYGEN",

author = "Matthew Herbert and Eleuterio Alvarez and Cole-Hamilton, {David John} and Francisco Montilla and Agustin Galindo",

year = "2010",

doi = "10.1039/c0cc00462f",

language = "English",

volume = "46",

pages = "5933--5935",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "32",

}

Olefin epoxidation by hydrogen peroxide catalysed by molybdenum complexes in ionic liquids and structural characterisation of the proposed intermediate dioxoperoxomolybdenum species. / Herbert, Matthew; Alvarez, Eleuterio; Cole-Hamilton, David John et al.
In: Chemical Communications, Vol. 46, No. 32, 2010, p. 5933-5935.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Olefin epoxidation by hydrogen peroxide catalysed by molybdenum complexes in ionic liquids and structural characterisation of the proposed intermediate dioxoperoxomolybdenum species

AU - Herbert, Matthew

AU - Alvarez, Eleuterio

AU - Cole-Hamilton, David John

AU - Montilla, Francisco

AU - Galindo, Agustin

PY - 2010

Y1 - 2010

N2 - The complex [Mo4O16(dmpz)(6)] (1) has been isolated as part of a study of oxodiperoxomolybdenum catalysed epoxidation of olefin substrates with hydrogen peroxide in ionic liquids. Notably, 1 is the first dioxoperoxomolybdenum species to be structurally characterised.

AB - The complex [Mo4O16(dmpz)(6)] (1) has been isolated as part of a study of oxodiperoxomolybdenum catalysed epoxidation of olefin substrates with hydrogen peroxide in ionic liquids. Notably, 1 is the first dioxoperoxomolybdenum species to be structurally characterised.

KW - DIPEROXO COMPLEXES

KW - PEROXOMOLYBDENUM COMPLEXES

KW - OXIDATION

KW - MECHANISM

KW - REACTIVITY

KW - SULFOXIDES

KW - SULFIDES

KW - ALKENES

KW - OXIDANT

KW - OXYGEN

UR - http://www.scopus.com/inward/record.url?scp=77955377355&partnerID=8YFLogxK

U2 - 10.1039/c0cc00462f

DO - 10.1039/c0cc00462f

M3 - Article

SN - 1359-7345

VL - 46

SP - 5933

EP - 5935

JO - Chemical Communications

JF - Chemical Communications

IS - 32

ER -

Olefin epoxidation by hydrogen peroxide catalysed by molybdenum complexes in ionic liquids and structural characterisation of the proposed intermediate dioxoperoxomolybdenum species

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this