Octahydro-1H,5H,7H-dipyrrolo[1,2-c:1',2'-f][1,3,6]oxadiazocine-5-thione

R. Alan Aitken; Karamat Ali

doi:10.3390/M993

Octahydro-1H,5H,7H-dipyrrolo[1,2-c:1',2'-f][1,3,6]oxadiazocine-5-thione

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Abstract

A minor byproduct in the reaction of (S)-prolinol with thiophosgene in the presence of triethylamine is identified as a novel tricyclic dipyrrolidino-1,3,6-oxadiazocane-2-thione, the first example of such a ring system, and a representative of the uncommon but useful 1,3,6-oxadiazocanes. A mechanism is proposed for its formation.

Original language	English
Article number	M993
Number of pages	5
Journal	Molbank
Volume	2018
DOIs	https://doi.org/10.3390/M993
Publication status	Published - 27 Apr 2018

Keywords

1,3,6-oxadiazocane
1,3,6-oxadiazocine-2-thione
NMR spectra

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10.3390/M993Licence: CC BY

Aitken_2018_Molbank_Octahydro_CCBY-VoR
© 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
Final published version, 423 KBLicence: CC BY

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abstract = "A minor byproduct in the reaction of (S)-prolinol with thiophosgene in the presence of triethylamine is identified as a novel tricyclic dipyrrolidino-1,3,6-oxadiazocane-2-thione, the first example of such a ring system, and a representative of the uncommon but useful 1,3,6-oxadiazocanes. A mechanism is proposed for its formation.",

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doi = "10.3390/M993",

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T1 - Octahydro-1H,5H,7H-dipyrrolo[1,2-c:1',2'-f][1,3,6]oxadiazocine-5-thione

AU - Aitken, R. Alan

AU - Ali, Karamat

PY - 2018/4/27

Y1 - 2018/4/27

N2 - A minor byproduct in the reaction of (S)-prolinol with thiophosgene in the presence of triethylamine is identified as a novel tricyclic dipyrrolidino-1,3,6-oxadiazocane-2-thione, the first example of such a ring system, and a representative of the uncommon but useful 1,3,6-oxadiazocanes. A mechanism is proposed for its formation.

AB - A minor byproduct in the reaction of (S)-prolinol with thiophosgene in the presence of triethylamine is identified as a novel tricyclic dipyrrolidino-1,3,6-oxadiazocane-2-thione, the first example of such a ring system, and a representative of the uncommon but useful 1,3,6-oxadiazocanes. A mechanism is proposed for its formation.

KW - 1,3,6-oxadiazocane

KW - 1,3,6-oxadiazocine-2-thione

KW - NMR spectra

U2 - 10.3390/M993

DO - 10.3390/M993

M3 - Article

SN - 1422-8599

VL - 2018

JO - Molbank

JF - Molbank

M1 - M993

ER -

Octahydro-1H,5H,7H-dipyrrolo[1,2-c:1',2'-f][1,3,6]oxadiazocine-5-thione

Abstract

Keywords

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