Abstract
A minor byproduct in the reaction of (S)-prolinol with thiophosgene in the presence of triethylamine is identified as a novel tricyclic dipyrrolidino-1,3,6-oxadiazocane-2-thione, the first example of such a ring system, and a representative of the uncommon but useful 1,3,6-oxadiazocanes. A mechanism is proposed for its formation.
Original language | English |
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Article number | M993 |
Number of pages | 5 |
Journal | Molbank |
Volume | 2018 |
DOIs | |
Publication status | Published - 27 Apr 2018 |
Keywords
- 1,3,6-oxadiazocane
- 1,3,6-oxadiazocine-2-thione
- NMR spectra