o-anisylstannyl derivatives (o-MeOC6H4)(n)SnX4-n. Crystal structures of (o-An)(n)SnX4-n (n=2, X = Ph or I; n=1, X = Br)

G  Ferguson; J N  Low; J N  Ross; E J  Storey; J L  Wardell

doi:10.1515/MGMC.1999.22.7.453

o-anisylstannyl derivatives (o-MeOC6H4)(n)SnX4-n. Crystal structures of (o-An)(n)SnX4-n (n=2, X = Ph or I; n=1, X = Br)

G Ferguson
, J N Low
, J N Ross
, E J Storey
, J L Wardell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis of a series of o-anisylstannanes, (o-An)(n)SnX4-n (n = 4; n = 3, X = I or Br; n = 2, X = Ph, I or Br; n = 1, X = Br) are reported. The structures of (o-An)(2)SnPh2, (o-An)(2)SnI2 and o-AnSnBr(3) have been determined by X-ray crystallography. The intramolecular Sn---O separations in (o-An)(n)SnX4-n in the solid state decrease with the increasing Lewis acidity of the tin centre.

Original language	English
Pages (from-to)	453-462
Number of pages	10
Journal	Main Group Metal Chemistry
Volume	22
Issue number	7
DOIs	https://doi.org/10.1515/MGMC.1999.22.7.453
Publication status	Published - Jul 1999

Keywords

RAY-DIFFRACTION ANALYSIS
MULTINUCLEAR NMR
COORDINATION BEHAVIOR
TIN-COMPOUNDS
SN-119
SPECTRA
STATE
N=3-5
C-13

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title = "o-anisylstannyl derivatives (o-MeOC6H4)(n)SnX4-n. Crystal structures of (o-An)(n)SnX4-n (n=2, X = Ph or I; n=1, X = Br)",

abstract = "The synthesis of a series of o-anisylstannanes, (o-An)(n)SnX4-n (n = 4; n = 3, X = I or Br; n = 2, X = Ph, I or Br; n = 1, X = Br) are reported. The structures of (o-An)(2)SnPh2, (o-An)(2)SnI2 and o-AnSnBr(3) have been determined by X-ray crystallography. The intramolecular Sn---O separations in (o-An)(n)SnX4-n in the solid state decrease with the increasing Lewis acidity of the tin centre.",

keywords = "RAY-DIFFRACTION ANALYSIS, MULTINUCLEAR NMR, COORDINATION BEHAVIOR, TIN-COMPOUNDS, SN-119, SPECTRA, STATE, N=3-5, C-13",

author = "G Ferguson and Low, \{J N\} and Ross, \{J N\} and Storey, \{E J\} and Wardell, \{J L\}",

year = "1999",

month = jul,

doi = "10.1515/MGMC.1999.22.7.453",

language = "English",

volume = "22",

pages = "453--462",

journal = "Main Group Metal Chemistry",

issn = "2191-0219",

publisher = "de Gruyter",

number = "7",

}

TY - JOUR

T1 - o-anisylstannyl derivatives (o-MeOC6H4)(n)SnX4-n. Crystal structures of (o-An)(n)SnX4-n (n=2, X = Ph or I; n=1, X = Br)

AU - Ferguson, G

AU - Low, J N

AU - Ross, J N

AU - Storey, E J

AU - Wardell, J L

PY - 1999/7

Y1 - 1999/7

N2 - The synthesis of a series of o-anisylstannanes, (o-An)(n)SnX4-n (n = 4; n = 3, X = I or Br; n = 2, X = Ph, I or Br; n = 1, X = Br) are reported. The structures of (o-An)(2)SnPh2, (o-An)(2)SnI2 and o-AnSnBr(3) have been determined by X-ray crystallography. The intramolecular Sn---O separations in (o-An)(n)SnX4-n in the solid state decrease with the increasing Lewis acidity of the tin centre.

AB - The synthesis of a series of o-anisylstannanes, (o-An)(n)SnX4-n (n = 4; n = 3, X = I or Br; n = 2, X = Ph, I or Br; n = 1, X = Br) are reported. The structures of (o-An)(2)SnPh2, (o-An)(2)SnI2 and o-AnSnBr(3) have been determined by X-ray crystallography. The intramolecular Sn---O separations in (o-An)(n)SnX4-n in the solid state decrease with the increasing Lewis acidity of the tin centre.

KW - RAY-DIFFRACTION ANALYSIS

KW - MULTINUCLEAR NMR

KW - COORDINATION BEHAVIOR

KW - TIN-COMPOUNDS

KW - SN-119

KW - SPECTRA

KW - STATE

KW - N=3-5

KW - C-13

U2 - 10.1515/MGMC.1999.22.7.453

DO - 10.1515/MGMC.1999.22.7.453

M3 - Article

SN - 2191-0219

VL - 22

SP - 453

EP - 462

JO - Main Group Metal Chemistry

JF - Main Group Metal Chemistry

IS - 7

ER -

o-anisylstannyl derivatives (o-MeOC6H4)(n)SnX4-n. Crystal structures of (o-An)(n)SnX4-n (n=2, X = Ph or I; n=1, X = Br)

Abstract

Keywords

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