o-anisylstannyl derivatives (o-MeOC6H4)(n)SnX4-n. Crystal structures of (o-An)(n)SnX4-n (n=2, X = Ph or I; n=1, X = Br)

G Ferguson, J N Low, J N Ross, E J Storey, J L Wardell

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Abstract

The synthesis of a series of o-anisylstannanes, (o-An)(n)SnX4-n (n = 4; n = 3, X = I or Br; n = 2, X = Ph, I or Br; n = 1, X = Br) are reported. The structures of (o-An)(2)SnPh2, (o-An)(2)SnI2 and o-AnSnBr(3) have been determined by X-ray crystallography. The intramolecular Sn---O separations in (o-An)(n)SnX4-n in the solid state decrease with the increasing Lewis acidity of the tin centre.

Original languageEnglish
Pages (from-to)453-462
Number of pages10
JournalMain Group Metal Chemistry
Volume22
Issue number7
DOIs
Publication statusPublished - Jul 1999

Keywords

  • RAY-DIFFRACTION ANALYSIS
  • MULTINUCLEAR NMR
  • COORDINATION BEHAVIOR
  • TIN-COMPOUNDS
  • SN-119
  • SPECTRA
  • STATE
  • N=3-5
  • C-13

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