Nucleophilicities and Lewis Basicities of Isothiourea Derivatives

Biplab Maji; Caroline Joannesse; Tobias A. Nigst; Andrew D. Smith; Herbert Mayr

doi:10.1021/jo200803x

Nucleophilicities and Lewis Basicities of Isothiourea Derivatives

Biplab Maji
, Caroline Joannesse
, Tobias A. Nigst
, Andrew D. Smith
, Herbert Mayr

Research output: Contribution to journal › Article › peer-review

Abstract

Rate and equilibrium constants for the reactions of a series of isothioureas with benzhydrylium ions have been measured photometrically. The data were employed to determine the nucleophilicities and nucleofugalities of isothioureas and compare them with those of other organocatalysts.

Original language	English
Pages (from-to)	5104-5112
Number of pages	9
Journal	The Journal of Organic Chemistry
Volume	76
Issue number	12
DOIs	https://doi.org/10.1021/jo200803x
Publication status	Published - 17 Jun 2011

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N-Heterocyclic Carbenes as Asymmetric: N-Heterocyclic Carbenes as Asymmetric Organocatalysts: Reaction Development
Smith, A. (PI)
EPSRC
1/04/07 → 30/09/10
Project: Standard

Cite this

@article{72105a59cd484f7681c96195e5c3b180,

title = "Nucleophilicities and Lewis Basicities of Isothiourea Derivatives",

abstract = "Rate and equilibrium constants for the reactions of a series of isothioureas with benzhydrylium ions have been measured photometrically. The data were employed to determine the nucleophilicities and nucleofugalities of isothioureas and compare them with those of other organocatalysts.",

author = "Biplab Maji and Caroline Joannesse and Nigst, \{Tobias A.\} and Smith, \{Andrew D.\} and Herbert Mayr",

year = "2011",

month = jun,

day = "17",

doi = "10.1021/jo200803x",

language = "English",

volume = "76",

pages = "5104--5112",

journal = "The Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society (ACS)",

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TY - JOUR

T1 - Nucleophilicities and Lewis Basicities of Isothiourea Derivatives

AU - Maji, Biplab

AU - Joannesse, Caroline

AU - Nigst, Tobias A.

AU - Smith, Andrew D.

AU - Mayr, Herbert

PY - 2011/6/17

Y1 - 2011/6/17

N2 - Rate and equilibrium constants for the reactions of a series of isothioureas with benzhydrylium ions have been measured photometrically. The data were employed to determine the nucleophilicities and nucleofugalities of isothioureas and compare them with those of other organocatalysts.

AB - Rate and equilibrium constants for the reactions of a series of isothioureas with benzhydrylium ions have been measured photometrically. The data were employed to determine the nucleophilicities and nucleofugalities of isothioureas and compare them with those of other organocatalysts.

U2 - 10.1021/jo200803x

DO - 10.1021/jo200803x

M3 - Article

SN - 0022-3263

VL - 76

SP - 5104

EP - 5112

JO - The Journal of Organic Chemistry

JF - The Journal of Organic Chemistry

IS - 12

ER -

Nucleophilicities and Lewis Basicities of Isothiourea Derivatives

Abstract

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N-Heterocyclic Carbenes as Asymmetric: N-Heterocyclic Carbenes as Asymmetric Organocatalysts: Reaction Development

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