Nucleophilic Reactions of 2,4-(Naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide

Z Fei, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

2,4-(Naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide (1) is very reactive towards nucleophiles, undergoing cleavage of the P-2(mu -S)(2) ring. The reactions of compound I with different bases such as N,N,N ' ,N ' -tetramethyl-guanidine, morpholine, pyrrolidine or NH3 (g) gave the corresponding ammonium salts of 2-5 in nearly quantitative yield. An ammonium salt 6 was obtained when I was reacted with morpholine in the presence of triethylamine. The reaction of 1 with Et3N . 3HF leads to the formation of 7. The new compounds 2-7 formed from the reactions have been studied spectroscopically and for 2, 6 and 7 by X-ray crystallography. (C) 2001 Elsevier Science Ltd. All rights reserved.

Original languageEnglish
Pages (from-to)2577-2581
Number of pages5
JournalPolyhedron
Volume20
Publication statusPublished - 30 Aug 2001

Keywords

  • dithiadiphosphetane
  • heterocycles
  • NMR
  • X-ray crystal structures
  • P-S-N
  • RING-SYSTEMS
  • REAGENTS

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