Novel non-aqueous Fe(III)/Fe(II) redox couple for the catalytic oxidation of hydrogen sulfide to sulfur by air

G X  Hua; Q Z  Zhang; D  McManus; A M Z  Slawin; J D  Woollins

doi:10.1039/b513384j

Novel non-aqueous Fe(III)/Fe(II) redox couple for the catalytic oxidation of hydrogen sulfide to sulfur by air

G X Hua, Q Z Zhang, D McManus, A M Z Slawin, J D Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

A series of Fe(III) salts and organic solvents have been screened to develop novel non-aqueous catalysts for the conversion of H2S to sulfur. FeCl3/95% N-methylpyrrolidinone/5% H2O was found to be a most efficient non-aqueous system. The process chemistry, the proposed mechanism of catalytic oxidation of H2S, and the CV are discussed.

Original language	English
Pages (from-to)	1147-1156
Number of pages	10
Journal	Dalton Transactions
Issue number	9
DOIs	https://doi.org/10.1039/b513384j
Publication status	Published - 2006

Keywords

AQUEOUS-SOLUTION
DIOXYGEN COMPLEXES
MOLECULAR-OXYGEN
FERRIC ION
IRON(III)
THERMODYNAMICS
HYDROLYSIS
RUTHENIUM
CONSTANTS
CHLORIDE

Access to Document

10.1039/b513384j

Cite this

@article{42ccce7326d54a328de072610d05d22d,

title = "Novel non-aqueous Fe(III)/Fe(II) redox couple for the catalytic oxidation of hydrogen sulfide to sulfur by air",

abstract = "A series of Fe(III) salts and organic solvents have been screened to develop novel non-aqueous catalysts for the conversion of H2S to sulfur. FeCl3/95% N-methylpyrrolidinone/5% H2O was found to be a most efficient non-aqueous system. The process chemistry, the proposed mechanism of catalytic oxidation of H2S, and the CV are discussed.",

keywords = "AQUEOUS-SOLUTION, DIOXYGEN COMPLEXES, MOLECULAR-OXYGEN, FERRIC ION, IRON(III), THERMODYNAMICS, HYDROLYSIS, RUTHENIUM, CONSTANTS, CHLORIDE",

author = "Hua, {G X} and Zhang, {Q Z} and D McManus and Slawin, {A M Z} and Woollins, {J D}",

year = "2006",

doi = "10.1039/b513384j",

language = "English",

pages = "1147--1156",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "ROYAL SOC CHEMISTRY",

number = "9",

}

TY - JOUR

T1 - Novel non-aqueous Fe(III)/Fe(II) redox couple for the catalytic oxidation of hydrogen sulfide to sulfur by air

AU - Hua, G X

AU - Zhang, Q Z

AU - McManus, D

AU - Slawin, A M Z

AU - Woollins, J D

PY - 2006

Y1 - 2006

N2 - A series of Fe(III) salts and organic solvents have been screened to develop novel non-aqueous catalysts for the conversion of H2S to sulfur. FeCl3/95% N-methylpyrrolidinone/5% H2O was found to be a most efficient non-aqueous system. The process chemistry, the proposed mechanism of catalytic oxidation of H2S, and the CV are discussed.

AB - A series of Fe(III) salts and organic solvents have been screened to develop novel non-aqueous catalysts for the conversion of H2S to sulfur. FeCl3/95% N-methylpyrrolidinone/5% H2O was found to be a most efficient non-aqueous system. The process chemistry, the proposed mechanism of catalytic oxidation of H2S, and the CV are discussed.

KW - AQUEOUS-SOLUTION

KW - DIOXYGEN COMPLEXES

KW - MOLECULAR-OXYGEN

KW - FERRIC ION

KW - IRON(III)

KW - THERMODYNAMICS

KW - HYDROLYSIS

KW - RUTHENIUM

KW - CONSTANTS

KW - CHLORIDE

UR - http://www.scopus.com/inward/record.url?scp=32944455090&partnerID=8YFLogxK

U2 - 10.1039/b513384j

DO - 10.1039/b513384j

M3 - Article

SN - 1477-9226

SP - 1147

EP - 1156

JO - Dalton Transactions

JF - Dalton Transactions

IS - 9

ER -

Novel non-aqueous Fe(III)/Fe(II) redox couple for the catalytic oxidation of hydrogen sulfide to sulfur by air

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this