Novel layered perovskite SmBaMn2O5+δ for SOFCs anode material

Abdalla M. Abdalla; Shahzad Hossain; Pg Mohd Iskandar Petra; Cristian D. Savaniu; John T. S. Irvine; Abul K. Azad

doi:10.1016/j.matlet.2017.06.029

Novel layered perovskite SmBaMn₂O_5+δ for SOFCs anode material

Abdalla M. Abdalla, Shahzad Hossain, Pg Mohd Iskandar Petra, Cristian D. Savaniu, John T. S. Irvine, Abul K. Azad

Research output: Contribution to journal › Article › peer-review

Abstract

SmBaMn₂O_5+δ (SBMO), a novel layered perovskite compound with samarium based material (Sm⁺³) as rare earth doped in A-site was synthesized and processed by using dry chemistry method (solid state solution). Structural characterization of SBMO has been investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM). While, thermal and electrochemical testing were done by using thermogravimetric analysis (TGA) and current voltage measurements. The Rietveld analysis of XRD data shows that SBMO was crystallized in the orthorhombic structure with the Pmmm space group. The surface morphology images showed a porous structure which indicates that this material can be used as a potential electrode in solid oxide fuel cells (SOFCs). TGA result showed the mass loss of 0.022% for SmBaMn₂O_5+δ which is very small and indicates that the material is very stable. DC conductivity and performance test were done at RT in air atmosphere. The performance tests have done at 800 °C and 750 °C and the maximum power density was found to be 0.4 W/cm² at 800 °C.

Original language	English
Pages (from-to)	129-132
Number of pages	4
Journal	Materials Letters
Volume	204
Early online date	7 Jun 2017
DOIs	https://doi.org/10.1016/j.matlet.2017.06.029
Publication status	Published - 1 Oct 2017

Keywords

Layered pervoskite
Structural analysis
Power density measurements
SOFCs anode

Access to Document

10.1016/j.matlet.2017.06.029

Irvine_2017_ML_NovelLayered_AAM
© 2017 Elsevier Ltd. All rights reserved. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1016/j.matlet.2017.06.029
Accepted author manuscript, 719 KBLicence: CC BY-NC-ND

Cite this

@article{87bfeded88464fbb9761a29809673115,

title = "Novel layered perovskite SmBaMn2O5+δ for SOFCs anode material",

abstract = "SmBaMn2O5+δ (SBMO), a novel layered perovskite compound with samarium based material (Sm+3) as rare earth doped in A-site was synthesized and processed by using dry chemistry method (solid state solution). Structural characterization of SBMO has been investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM). While, thermal and electrochemical testing were done by using thermogravimetric analysis (TGA) and current voltage measurements. The Rietveld analysis of XRD data shows that SBMO was crystallized in the orthorhombic structure with the Pmmm space group. The surface morphology images showed a porous structure which indicates that this material can be used as a potential electrode in solid oxide fuel cells (SOFCs). TGA result showed the mass loss of 0.022% for SmBaMn2O5+δ which is very small and indicates that the material is very stable. DC conductivity and performance test were done at RT in air atmosphere. The performance tests have done at 800 °C and 750 °C and the maximum power density was found to be 0.4 W/cm2 at 800 °C.",

keywords = "Layered pervoskite, Structural analysis, Power density measurements, SOFCs anode",

author = "Abdalla, {Abdalla M.} and Shahzad Hossain and Petra, {Pg Mohd Iskandar} and Savaniu, {Cristian D.} and Irvine, {John T. S.} and Azad, {Abul K.}",

note = "The authors Abdalla M. Abdalla and Shahzad Hossain are thankful to the Graduate Research Office of Universiti Brunei Darussalam for Graduate Research Scholarship (GRS) for funding this research work done.",

year = "2017",

month = oct,

day = "1",

doi = "10.1016/j.matlet.2017.06.029",

language = "English",

volume = "204",

pages = "129--132",

journal = "Materials Letters",

issn = "0167-577X",

publisher = "Elsevier",

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TY - JOUR

T1 - Novel layered perovskite SmBaMn2O5+δ for SOFCs anode material

AU - Abdalla, Abdalla M.

AU - Hossain, Shahzad

AU - Petra, Pg Mohd Iskandar

AU - Savaniu, Cristian D.

AU - Irvine, John T. S.

AU - Azad, Abul K.

N1 - The authors Abdalla M. Abdalla and Shahzad Hossain are thankful to the Graduate Research Office of Universiti Brunei Darussalam for Graduate Research Scholarship (GRS) for funding this research work done.

PY - 2017/10/1

Y1 - 2017/10/1

N2 - SmBaMn2O5+δ (SBMO), a novel layered perovskite compound with samarium based material (Sm+3) as rare earth doped in A-site was synthesized and processed by using dry chemistry method (solid state solution). Structural characterization of SBMO has been investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM). While, thermal and electrochemical testing were done by using thermogravimetric analysis (TGA) and current voltage measurements. The Rietveld analysis of XRD data shows that SBMO was crystallized in the orthorhombic structure with the Pmmm space group. The surface morphology images showed a porous structure which indicates that this material can be used as a potential electrode in solid oxide fuel cells (SOFCs). TGA result showed the mass loss of 0.022% for SmBaMn2O5+δ which is very small and indicates that the material is very stable. DC conductivity and performance test were done at RT in air atmosphere. The performance tests have done at 800 °C and 750 °C and the maximum power density was found to be 0.4 W/cm2 at 800 °C.

AB - SmBaMn2O5+δ (SBMO), a novel layered perovskite compound with samarium based material (Sm+3) as rare earth doped in A-site was synthesized and processed by using dry chemistry method (solid state solution). Structural characterization of SBMO has been investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM). While, thermal and electrochemical testing were done by using thermogravimetric analysis (TGA) and current voltage measurements. The Rietveld analysis of XRD data shows that SBMO was crystallized in the orthorhombic structure with the Pmmm space group. The surface morphology images showed a porous structure which indicates that this material can be used as a potential electrode in solid oxide fuel cells (SOFCs). TGA result showed the mass loss of 0.022% for SmBaMn2O5+δ which is very small and indicates that the material is very stable. DC conductivity and performance test were done at RT in air atmosphere. The performance tests have done at 800 °C and 750 °C and the maximum power density was found to be 0.4 W/cm2 at 800 °C.

KW - Layered pervoskite

KW - Structural analysis

KW - Power density measurements

KW - SOFCs anode

U2 - 10.1016/j.matlet.2017.06.029

DO - 10.1016/j.matlet.2017.06.029

M3 - Article

SN - 0167-577X

VL - 204

SP - 129

EP - 132

JO - Materials Letters

JF - Materials Letters

ER -