Novel bimetallic lead(II) complexes of polydentate amine-phenol ligands

P Bhattacharyya, J Parr, A M Z Slawin

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10 Citations (Scopus)

Abstract

The polydentate amine-phenol ligands N(CH2CH2NHCH2C6H4OH-2)(3) (H3L1) and (2-HOC6H4CH2NH)(2)C2H4-1,2 (H2L2) prepared by reduction of the Schiff bases H(3)saltren and H(2)salen react with lead(II) acetate trihydrate to form complexes 1 and 2 respectively, both of which are dimeric in the solid state and fluxional in solution at ambient temperatures. These complexes are characterised by IR, microanalysis and single crystal X-ray diffraction. (C) 1999 Elsevier Science S.A. All rights reserved.

Original languageEnglish
Pages (from-to)113-115
Number of pages3
JournalInorganic Chemistry Communications
Volume2
Issue number3
Publication statusPublished - Mar 1999

Keywords

  • crystal structures
  • lead(II) complexes
  • polydentate amine-phenol complexes
  • dinuclear complexes
  • CRYSTAL-STRUCTURE
  • SELECTIVITY
  • MACROCYCLE
  • TEMPLATE
  • BRIDGES
  • AGENTS

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