TY - JOUR
T1 - N,N'-Dithiobis(phthalimide)-nitrobenzene (2/1): a Pn solvate with localised solvent molecules lordered head-to-tail in channels
AU - Bowes, F
AU - Ferguson, G
AU - Glidewell, Christopher
AU - Low, JN
AU - Quesada, A
PY - 2002/9
Y1 - 2002/9
N2 - N,N'-Dithiobisphthalimide crystallizes from nitrobenzene solution as a solvate, 2C(16)H(8)N(2)O(4)S(2).C6H5NO2, having space group Pn. The bisphthalimide molecules are linked by CD H ... O hydrogen bonds and by aromatic pi-pi-stacking interactions, forming a framework enclosing continuous channels running along the [100] direction and accounting for ca 20% of the unit-cell volume. The nitrobenzene molecules lie in these channels, ordered in a head-to-tail fashion and linked to the bisphthalimide framework by C-H ... O and C-H ... (arene) hydrogen bonds.
AB - N,N'-Dithiobisphthalimide crystallizes from nitrobenzene solution as a solvate, 2C(16)H(8)N(2)O(4)S(2).C6H5NO2, having space group Pn. The bisphthalimide molecules are linked by CD H ... O hydrogen bonds and by aromatic pi-pi-stacking interactions, forming a framework enclosing continuous channels running along the [100] direction and accounting for ca 20% of the unit-cell volume. The nitrobenzene molecules lie in these channels, ordered in a head-to-tail fashion and linked to the bisphthalimide framework by C-H ... O and C-H ... (arene) hydrogen bonds.
U2 - 10.1107/S0108270102012830
DO - 10.1107/S0108270102012830
M3 - Article
SN - 0108-2701
VL - C58
SP - o551-o554
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
ER -