N,N '-Dimethylpiperazinium(2+) phosphonoacetate: hydrogen-bonded anion sheets containing cation-templated R-6(6) (28) rings

D M M  Farrell; G  Ferguson; A J  Lough; C  Glidewell

N,N '-Dimethylpiperazinium(2+) phosphonoacetate: hydrogen-bonded anion sheets containing cation-templated R-6(6) (28) rings

D M M Farrell, G Ferguson, A J Lough, C Glidewell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, C6H16N22+. 2C(2)H(4)O(5)P(-), the cations lie across centres of inversion; in the anions, two of the H-atom sites have 0.50 occupancy. The anions are linked by short OD H . . .O hydrogen bonds [O . . .O 2.465 (3)-2.612 (3) Angstrom and O- H . . .O 165-171 degrees] into sheets of alternating R-2(2) (12) and R-6(6) (28) rings, both of which are centrosymmetric; the cations lie at the centres of the larger rings linked to the anion sheet by ND H . . .O hydrogen bonds [N . . .O 2.642 (2) Angstrom and N-H . . .O 176 degrees].

Original language	English
Pages (from-to)	952-954
Number of pages	3
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	57
Publication status	Published - Aug 2001

Keywords

ACID

Cite this

@article{98624518480641c0bf07dc256a0a6df7,

title = "N,N '-Dimethylpiperazinium(2+) phosphonoacetate: hydrogen-bonded anion sheets containing cation-templated R-6(6) (28) rings",

abstract = "In the title compound, C6H16N22+. 2C(2)H(4)O(5)P(-), the cations lie across centres of inversion; in the anions, two of the H-atom sites have 0.50 occupancy. The anions are linked by short OD H . . .O hydrogen bonds [O . . .O 2.465 (3)-2.612 (3) Angstrom and O- H . . .O 165-171 degrees] into sheets of alternating R-2(2) (12) and R-6(6) (28) rings, both of which are centrosymmetric; the cations lie at the centres of the larger rings linked to the anion sheet by ND H . . .O hydrogen bonds [N . . .O 2.642 (2) Angstrom and N-H . . .O 176 degrees].",

keywords = "ACID",

author = "Farrell, {D M M} and G Ferguson and Lough, {A J} and C Glidewell",

year = "2001",

month = aug,

language = "English",

volume = "57",

pages = "952--954",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - N,N '-Dimethylpiperazinium(2+) phosphonoacetate: hydrogen-bonded anion sheets containing cation-templated R-6(6) (28) rings

AU - Farrell, D M M

AU - Ferguson, G

AU - Lough, A J

AU - Glidewell, C

PY - 2001/8

Y1 - 2001/8

N2 - In the title compound, C6H16N22+. 2C(2)H(4)O(5)P(-), the cations lie across centres of inversion; in the anions, two of the H-atom sites have 0.50 occupancy. The anions are linked by short OD H . . .O hydrogen bonds [O . . .O 2.465 (3)-2.612 (3) Angstrom and O- H . . .O 165-171 degrees] into sheets of alternating R-2(2) (12) and R-6(6) (28) rings, both of which are centrosymmetric; the cations lie at the centres of the larger rings linked to the anion sheet by ND H . . .O hydrogen bonds [N . . .O 2.642 (2) Angstrom and N-H . . .O 176 degrees].

AB - In the title compound, C6H16N22+. 2C(2)H(4)O(5)P(-), the cations lie across centres of inversion; in the anions, two of the H-atom sites have 0.50 occupancy. The anions are linked by short OD H . . .O hydrogen bonds [O . . .O 2.465 (3)-2.612 (3) Angstrom and O- H . . .O 165-171 degrees] into sheets of alternating R-2(2) (12) and R-6(6) (28) rings, both of which are centrosymmetric; the cations lie at the centres of the larger rings linked to the anion sheet by ND H . . .O hydrogen bonds [N . . .O 2.642 (2) Angstrom and N-H . . .O 176 degrees].

KW - ACID

M3 - Article

SN - 1600-5759

VL - 57

SP - 952

EP - 954

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

N,N '-Dimethylpiperazinium(2+) phosphonoacetate: hydrogen-bonded anion sheets containing cation-templated R-6(6) (28) rings

Abstract

Keywords

Fingerprint

Cite this