N,N-Chelate-control on the regioselectivity in acetate-assisted C–H activation

Warren B. Cross; Eric G. Hope; Yi Hsien Lin; Stuart A. Macgregor; Kuldip Singh; Gregory A. Solan; Nurhusna Yahya

doi:10.1039/c3cc38697j

N,N-Chelate-control on the regioselectivity in acetate-assisted C–H activation

Warren B. Cross, Eric G. Hope, Yi Hsien Lin, Stuart A. Macgregor, Kuldip Singh, Gregory A. Solan^*, Nurhusna Yahya

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Bidentate N,N-pyridylimine or N,N-pyridylamine donors are effective chelating ligands for regiospecific C–H activation at the peri-(C₈)-position of a naphthyl ring on reaction with palladium(ii) acetate; DFT calculations show N,N-chelates bias the cyclopalladation towards 6-membered ring products.

Original language	English
Pages (from-to)	1918-1920
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	19
DOIs	https://doi.org/10.1039/c3cc38697j
Publication status	Published - 7 Feb 2013

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title = "N,N-Chelate-control on the regioselectivity in acetate-assisted C–H activation",

abstract = "Bidentate N,N-pyridylimine or N,N-pyridylamine donors are effective chelating ligands for regiospecific C–H activation at the peri-(C8)-position of a naphthyl ring on reaction with palladium(ii) acetate; DFT calculations show N,N-chelates bias the cyclopalladation towards 6-membered ring products.",

author = "Cross, \{Warren B.\} and Hope, \{Eric G.\} and Lin, \{Yi Hsien\} and Macgregor, \{Stuart A.\} and Kuldip Singh and Solan, \{Gregory A.\} and Nurhusna Yahya",

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doi = "10.1039/c3cc38697j",

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T1 - N,N-Chelate-control on the regioselectivity in acetate-assisted C–H activation

AU - Cross, Warren B.

AU - Hope, Eric G.

AU - Lin, Yi Hsien

AU - Macgregor, Stuart A.

AU - Singh, Kuldip

AU - Solan, Gregory A.

AU - Yahya, Nurhusna

PY - 2013/2/7

Y1 - 2013/2/7

N2 - Bidentate N,N-pyridylimine or N,N-pyridylamine donors are effective chelating ligands for regiospecific C–H activation at the peri-(C8)-position of a naphthyl ring on reaction with palladium(ii) acetate; DFT calculations show N,N-chelates bias the cyclopalladation towards 6-membered ring products.

AB - Bidentate N,N-pyridylimine or N,N-pyridylamine donors are effective chelating ligands for regiospecific C–H activation at the peri-(C8)-position of a naphthyl ring on reaction with palladium(ii) acetate; DFT calculations show N,N-chelates bias the cyclopalladation towards 6-membered ring products.

UR - https://www.scopus.com/pages/publications/84873691563

U2 - 10.1039/c3cc38697j

DO - 10.1039/c3cc38697j

M3 - Article

AN - SCOPUS:84873691563

SN - 1359-7345

VL - 49

SP - 1918

EP - 1920

JO - Chemical Communications

JF - Chemical Communications

IS - 19

ER -

N,N-Chelate-control on the regioselectivity in acetate-assisted C–H activation

Abstract

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