NMR study of GdFe2Hx hydrides

V  Prochazka; C  Kapusta; P C  Riedi; J  Zukrowski

doi:10.1016/j.jallcom.2005.02.071

NMR study of GdFe2Hx hydrides

V Prochazka, C Kapusta, P C Riedi, J Zukrowski

School of Physics and Astronomy

Research output: Contribution to journal › Article › peer-review

Abstract

NMR study of GdFe2Hx (x = 0, 1.05, 1.7, 2.45, 2.85) hydrides are reported. The values of x chosen at characteristic points of the phase diagram correspond to single phase compounds. Spin echo spectra at zero field and relaxation times T-2 have been measured on powder samples at 4.2 K. The resonances of Gd-155, Gd-157 and H-1 have been identified and the values of the hyperfine fields are obtained. The results are analysed in terms of hydrogen occupation of A2B2 sites and a comparison of hydrogen hyperfine field with dipolar fields at H sites evaluated from lattice sums is made. (c) 2005 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	163-164
Number of pages	2
Journal	Journal of Alloys and Compounds
Volume	404
DOIs	https://doi.org/10.1016/j.jallcom.2005.02.071
Publication status	Published - 8 Dec 2005

Keywords

hydride
NMR
hyperfine field
dipolar field

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10.1016/j.jallcom.2005.02.071

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title = "NMR study of GdFe2Hx hydrides",

abstract = "NMR study of GdFe2Hx (x = 0, 1.05, 1.7, 2.45, 2.85) hydrides are reported. The values of x chosen at characteristic points of the phase diagram correspond to single phase compounds. Spin echo spectra at zero field and relaxation times T-2 have been measured on powder samples at 4.2 K. The resonances of Gd-155, Gd-157 and H-1 have been identified and the values of the hyperfine fields are obtained. The results are analysed in terms of hydrogen occupation of A2B2 sites and a comparison of hydrogen hyperfine field with dipolar fields at H sites evaluated from lattice sums is made. (c) 2005 Elsevier B.V. All rights reserved.",

keywords = "hydride, NMR, hyperfine field, dipolar field",

author = "V Prochazka and C Kapusta and Riedi, {P C} and J Zukrowski",

year = "2005",

month = dec,

day = "8",

doi = "10.1016/j.jallcom.2005.02.071",

language = "English",

volume = "404",

pages = "163--164",

journal = "Journal of Alloys and Compounds",

issn = "0925-8388",

publisher = "Elsevier",

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TY - JOUR

T1 - NMR study of GdFe2Hx hydrides

AU - Prochazka, V

AU - Kapusta, C

AU - Riedi, P C

AU - Zukrowski, J

PY - 2005/12/8

Y1 - 2005/12/8

N2 - NMR study of GdFe2Hx (x = 0, 1.05, 1.7, 2.45, 2.85) hydrides are reported. The values of x chosen at characteristic points of the phase diagram correspond to single phase compounds. Spin echo spectra at zero field and relaxation times T-2 have been measured on powder samples at 4.2 K. The resonances of Gd-155, Gd-157 and H-1 have been identified and the values of the hyperfine fields are obtained. The results are analysed in terms of hydrogen occupation of A2B2 sites and a comparison of hydrogen hyperfine field with dipolar fields at H sites evaluated from lattice sums is made. (c) 2005 Elsevier B.V. All rights reserved.

AB - NMR study of GdFe2Hx (x = 0, 1.05, 1.7, 2.45, 2.85) hydrides are reported. The values of x chosen at characteristic points of the phase diagram correspond to single phase compounds. Spin echo spectra at zero field and relaxation times T-2 have been measured on powder samples at 4.2 K. The resonances of Gd-155, Gd-157 and H-1 have been identified and the values of the hyperfine fields are obtained. The results are analysed in terms of hydrogen occupation of A2B2 sites and a comparison of hydrogen hyperfine field with dipolar fields at H sites evaluated from lattice sums is made. (c) 2005 Elsevier B.V. All rights reserved.

KW - hydride

KW - NMR

KW - hyperfine field

KW - dipolar field

U2 - 10.1016/j.jallcom.2005.02.071

DO - 10.1016/j.jallcom.2005.02.071

M3 - Article

SN - 0925-8388

VL - 404

SP - 163

EP - 164

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

ER -

NMR study of GdFe2Hx hydrides

Abstract

Keywords

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