NMR Studies of Platinum bisphosphine complexes of phenylphosphonamidodiselenoate

Jaqueline Garland, David B. Cordes, Alexandra M.Z. Slawin, J. Derek Woollins

Research output: Contribution to journalArticlepeer-review


A series of platinum (II) bisphosphine complexes 1-20 [Pt(R’NH(Ph)PSe2)(PR3)2] (where R = Ph3, Ph2Me, Me2Ph, PMe3 and R’ = iPr, nBu, sBu, tBu, Benz) have been prepared by reaction of cis-[Pt(PR3)2Cl2)] and the alkyl ammonium salt of the ligand. The novel compounds were characterised by multinuclear NMR, and in one case X-Ray crystallography. The molecular structures of two ligand salts and [Pt(sBu’NH(Ph)PSe2)(PPh3)2] are reported.

Original languageEnglish
Early online date13 May 2015
Publication statusPublished - 2015


  • Selenium
  • Phosphorus
  • Platinum
  • Complex
  • X-ray structure


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