Nickel(II) promoted P-N bond cleavage of (Ph2PNH)2CS. X-ray crystal structure of trans-[Ni{Ph2PNHC(S)NH2-P,S}2]Cl2

P Bhattacharyya; Alexandra Martha Zoya Slawin; John Derek Woollins

Nickel(II) promoted P-N bond cleavage of (Ph₂PNH)₂CS. X-ray crystal structure of trans-[Ni{Ph₂PNHC(S)NH₂-P,S}₂]Cl₂

P Bhattacharyya, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Other contribution

Abstract

The reaction of (Ph2PNH)(2)CS with nickel(II) chloride hexahydrate in methanol proceeds with methanolysis of a P-N bond to give trans-[Ni{Ph2PNHC(S)NH2-P, S}(2)]Cl-2, whose structure has been confirmed by X-ray crystallography. (C) 2001 Elsevier Science B.V. All rights reserved.

Original language	English
Volume	4
Publication status	Published - Apr 2001

Keywords

nickel
X-ray crystal structure
phosphine
P-N bond
SUBSTITUTED N,N'-DIMETHYLTHIOUREA COMPOUNDS
COORDINATION CHEMISTRY
DERIVATIVES
COMPLEXES
OXIDATION
LIGANDS
UREA

Cite this

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title = "Nickel(II) promoted P-N bond cleavage of (Ph2PNH)2CS. X-ray crystal structure of trans-[Ni{Ph2PNHC(S)NH2-P,S}2]Cl2",

abstract = "The reaction of (Ph2PNH)(2)CS with nickel(II) chloride hexahydrate in methanol proceeds with methanolysis of a P-N bond to give trans-[Ni{Ph2PNHC(S)NH2-P, S}(2)]Cl-2, whose structure has been confirmed by X-ray crystallography. (C) 2001 Elsevier Science B.V. All rights reserved.",

keywords = "nickel, X-ray crystal structure, phosphine, P-N bond, SUBSTITUTED N,N'-DIMETHYLTHIOUREA COMPOUNDS, COORDINATION CHEMISTRY, DERIVATIVES, COMPLEXES, OXIDATION, LIGANDS, UREA",

author = "P Bhattacharyya and Slawin, {Alexandra Martha Zoya} and Woollins, {John Derek}",

note = "Inorg Chem Comm",

year = "2001",

month = apr,

language = "English",

volume = "4",

type = "Other",

}

TY - GEN

T1 - Nickel(II) promoted P-N bond cleavage of (Ph2PNH)2CS. X-ray crystal structure of trans-[Ni{Ph2PNHC(S)NH2-P,S}2]Cl2

AU - Bhattacharyya, P

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, John Derek

N1 - Inorg Chem Comm

PY - 2001/4

Y1 - 2001/4

N2 - The reaction of (Ph2PNH)(2)CS with nickel(II) chloride hexahydrate in methanol proceeds with methanolysis of a P-N bond to give trans-[Ni{Ph2PNHC(S)NH2-P, S}(2)]Cl-2, whose structure has been confirmed by X-ray crystallography. (C) 2001 Elsevier Science B.V. All rights reserved.

AB - The reaction of (Ph2PNH)(2)CS with nickel(II) chloride hexahydrate in methanol proceeds with methanolysis of a P-N bond to give trans-[Ni{Ph2PNHC(S)NH2-P, S}(2)]Cl-2, whose structure has been confirmed by X-ray crystallography. (C) 2001 Elsevier Science B.V. All rights reserved.

KW - nickel

KW - X-ray crystal structure

KW - phosphine

KW - P-N bond

KW - SUBSTITUTED N,N'-DIMETHYLTHIOUREA COMPOUNDS

KW - COORDINATION CHEMISTRY

KW - DERIVATIVES

KW - COMPLEXES

KW - OXIDATION

KW - LIGANDS

KW - UREA

UR - http://www.scopus.com/inward/record.url?scp=0035056011&partnerID=8YFLogxK

M3 - Other contribution

VL - 4

ER -

Nickel(II) promoted P-N bond cleavage of (Ph₂PNH)₂CS. X-ray crystal structure of trans-[Ni{Ph₂PNHC(S)NH₂-P,S}₂]Cl₂

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