Nickel(II) promoted P-N bond cleavage of (Ph2PNH)2CS. X-ray crystal structure of trans-[Ni{Ph2PNHC(S)NH2-P,S}2]Cl2

P Bhattacharyya, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Other contribution

3 Citations (Scopus)

Abstract

The reaction of (Ph2PNH)(2)CS with nickel(II) chloride hexahydrate in methanol proceeds with methanolysis of a P-N bond to give trans-[Ni{Ph2PNHC(S)NH2-P, S}(2)]Cl-2, whose structure has been confirmed by X-ray crystallography. (C) 2001 Elsevier Science B.V. All rights reserved.

Original languageEnglish
Volume4
Publication statusPublished - Apr 2001

Keywords

  • nickel
  • X-ray crystal structure
  • phosphine
  • P-N bond
  • SUBSTITUTED N,N'-DIMETHYLTHIOUREA COMPOUNDS
  • COORDINATION CHEMISTRY
  • DERIVATIVES
  • COMPLEXES
  • OXIDATION
  • LIGANDS
  • UREA

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