Nickel-catalysed carboxylation of organoboronates

Yusuke Makida; Enrico Marelli; Alexandra M. Z. Slawin; Steven P. Nolan

doi:10.1039/C4CC03650F

Nickel-catalysed carboxylation of organoboronates

Yusuke Makida, Enrico Marelli, Alexandra M. Z. Slawin, Steven P. Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

A nickel/N-heterocyclic carbene (NHC) catalysed carboxylation of aryl-, heteroaryl- and alkenylboronates, affording the corresponding carboxylic acids, has been developed. This transformation proceeds under one atmosphere of CO₂ with a broad range of substrates and exhibits good functional group compatibility.

Original language	English
Pages (from-to)	8010-8013
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	59
DOIs	https://doi.org/10.1039/C4CC03650F
Publication status	Published - 5 Jun 2014

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10.1039/C4CC03650F

Makida_2014_CC_Nickel
© Royal Society of Chemistry 2014. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (http://creativecommons.org/licenses/by/3.0/).
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title = "Nickel-catalysed carboxylation of organoboronates",

abstract = "A nickel/N-heterocyclic carbene (NHC) catalysed carboxylation of aryl-, heteroaryl- and alkenylboronates, affording the corresponding carboxylic acids, has been developed. This transformation proceeds under one atmosphere of CO2 with a broad range of substrates and exhibits good functional group compatibility.",

author = "Yusuke Makida and Enrico Marelli and Slawin, {Alexandra M. Z.} and Nolan, {Steven P.}",

note = "The authors acknowledge the ERC (Advanced Researcher award-FUNCAT, CO2Chem) and King Saud University for funding and the EPSRC NMSSC in Swansea for mass spectrometric analyses. SPN is a Royal Society Wolfson Research Merit Award holder.",

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T1 - Nickel-catalysed carboxylation of organoboronates

AU - Makida, Yusuke

AU - Marelli, Enrico

AU - Slawin, Alexandra M. Z.

AU - Nolan, Steven P.

N1 - The authors acknowledge the ERC (Advanced Researcher award-FUNCAT, CO2Chem) and King Saud University for funding and the EPSRC NMSSC in Swansea for mass spectrometric analyses. SPN is a Royal Society Wolfson Research Merit Award holder.

PY - 2014/6/5

Y1 - 2014/6/5

N2 - A nickel/N-heterocyclic carbene (NHC) catalysed carboxylation of aryl-, heteroaryl- and alkenylboronates, affording the corresponding carboxylic acids, has been developed. This transformation proceeds under one atmosphere of CO2 with a broad range of substrates and exhibits good functional group compatibility.

AB - A nickel/N-heterocyclic carbene (NHC) catalysed carboxylation of aryl-, heteroaryl- and alkenylboronates, affording the corresponding carboxylic acids, has been developed. This transformation proceeds under one atmosphere of CO2 with a broad range of substrates and exhibits good functional group compatibility.

UR - http://www.rsc.org/suppdata/cc/c4/c4cc03650f/c4cc03650f1.pdf

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DO - 10.1039/C4CC03650F

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VL - 50

SP - 8010

EP - 8013

JO - Chemical Communications

JF - Chemical Communications

IS - 59

ER -

Nickel-catalysed carboxylation of organoboronates

Abstract

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FUNCAT: EU FP7 ERC Advanced Grant - FUNCAT - Fundamental Studies in Organometallic Chemistry and Homogeneous Catalysis

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Nickel-catalysed carboxylation of organoboronates

Abstract

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Projects

FUNCAT: EU FP7 ERC Advanced Grant - FUNCAT - Fundamental Studies in Organometallic Chemistry and Homogeneous Catalysis

Cite this