(NHC)CuI (NHC = N-Heterocyclic Carbene) Complexes as Efficient Catalysts for the Reduction of Carbonyl Compounds

H Kaur; F K Zinn; E D Stevens; Steven Patrick Nolan

doi:10.1021/om034285a

(NHC)CuI (NHC = N-Heterocyclic Carbene) Complexes as Efficient Catalysts for the Reduction of Carbonyl Compounds

H Kaur, F K Zinn, E D Stevens, Steven Patrick Nolan

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Abstract

The hydrosilylation of various ketones is mediated by an imidazolium salt/Cu(I) salt system or by a well-defined (NHC)CuCl (NHC = N-heterocyclic carbene) catalyst precursor system. Reactions are conducted at room temperature. The synthesis and characterization of well-defined (NHC)CuCl complexes are described.

Original language	English
Pages (from-to)	1157-1160
Number of pages	4
Journal	Organometallics
Volume	23
Issue number	5
DOIs	https://doi.org/10.1021/om034285a
Publication status	Published - 1 Mar 2004

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abstract = "The hydrosilylation of various ketones is mediated by an imidazolium salt/Cu(I) salt system or by a well-defined (NHC)CuCl (NHC = N-heterocyclic carbene) catalyst precursor system. Reactions are conducted at room temperature. The synthesis and characterization of well-defined (NHC)CuCl complexes are described. ",

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AU - Zinn, F K

AU - Stevens, E D

AU - Nolan, Steven Patrick

PY - 2004/3/1

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N2 - The hydrosilylation of various ketones is mediated by an imidazolium salt/Cu(I) salt system or by a well-defined (NHC)CuCl (NHC = N-heterocyclic carbene) catalyst precursor system. Reactions are conducted at room temperature. The synthesis and characterization of well-defined (NHC)CuCl complexes are described.

AB - The hydrosilylation of various ketones is mediated by an imidazolium salt/Cu(I) salt system or by a well-defined (NHC)CuCl (NHC = N-heterocyclic carbene) catalyst precursor system. Reactions are conducted at room temperature. The synthesis and characterization of well-defined (NHC)CuCl complexes are described.

U2 - 10.1021/om034285a

DO - 10.1021/om034285a

M3 - Article

SN - 0276-7333

VL - 23

SP - 1157

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JO - Organometallics

JF - Organometallics

IS - 5

ER -

(NHC)CuI (NHC = N-Heterocyclic Carbene) Complexes as Efficient Catalysts for the Reduction of Carbonyl Compounds

Abstract

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