New phosphazene chains and ligands in complexes and clusters

A M Z  Slawin; M B  Smith; J D  Woollins

doi:10.1039/CC9960002095

New phosphazene chains and ligands in complexes and clusters

A M Z Slawin, M B Smith, J D Woollins

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Abstract

Ph(2)PNP(Ph)(2)P(Ph)(2)NPPh(2) 1 is oxidised by S or Se to give Ph(2)P(E)NP(Ph)(2)P(Ph)(2)NP(E)Ph(2) (E = S 2, E = Se 3), endcapped by ClAu units or coordinated as a chelate with (CH3)(2)Pt; the diselenide 3 reacts with [Ru-3(CO)(12)] via oxidative addition of Se2- ions acid expulsion of a PPh(2)(-) group to form a novel cluster containing the [Ph(2)PNP(Ph)(2)NPPh(2)](-) ligand which is ligated by two terminal P atoms and by one N atom.

Original language	English
Pages (from-to)	2095-2096
Number of pages	2
Journal	Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/CC9960002095
Publication status	Published - 7 Sept 1996

Keywords

POLYFUNCTIONAL MOLECULES
CHEMISTRY
ANION

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10.1039/CC9960002095

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title = "New phosphazene chains and ligands in complexes and clusters",

abstract = "Ph(2)PNP(Ph)(2)P(Ph)(2)NPPh(2) 1 is oxidised by S or Se to give Ph(2)P(E)NP(Ph)(2)P(Ph)(2)NP(E)Ph(2) (E = S 2, E = Se 3), endcapped by ClAu units or coordinated as a chelate with (CH3)(2)Pt; the diselenide 3 reacts with [Ru-3(CO)(12)] via oxidative addition of Se2- ions acid expulsion of a PPh(2)(-) group to form a novel cluster containing the [Ph(2)PNP(Ph)(2)NPPh(2)](-) ligand which is ligated by two terminal P atoms and by one N atom.",

keywords = "POLYFUNCTIONAL MOLECULES, CHEMISTRY, ANION",

author = "Slawin, {A M Z} and Smith, {M B} and Woollins, {J D}",

year = "1996",

month = sep,

day = "7",

doi = "10.1039/CC9960002095",

language = "English",

pages = "2095--2096",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "17",

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TY - JOUR

T1 - New phosphazene chains and ligands in complexes and clusters

AU - Slawin, A M Z

AU - Smith, M B

AU - Woollins, J D

PY - 1996/9/7

Y1 - 1996/9/7

N2 - Ph(2)PNP(Ph)(2)P(Ph)(2)NPPh(2) 1 is oxidised by S or Se to give Ph(2)P(E)NP(Ph)(2)P(Ph)(2)NP(E)Ph(2) (E = S 2, E = Se 3), endcapped by ClAu units or coordinated as a chelate with (CH3)(2)Pt; the diselenide 3 reacts with [Ru-3(CO)(12)] via oxidative addition of Se2- ions acid expulsion of a PPh(2)(-) group to form a novel cluster containing the [Ph(2)PNP(Ph)(2)NPPh(2)](-) ligand which is ligated by two terminal P atoms and by one N atom.

AB - Ph(2)PNP(Ph)(2)P(Ph)(2)NPPh(2) 1 is oxidised by S or Se to give Ph(2)P(E)NP(Ph)(2)P(Ph)(2)NP(E)Ph(2) (E = S 2, E = Se 3), endcapped by ClAu units or coordinated as a chelate with (CH3)(2)Pt; the diselenide 3 reacts with [Ru-3(CO)(12)] via oxidative addition of Se2- ions acid expulsion of a PPh(2)(-) group to form a novel cluster containing the [Ph(2)PNP(Ph)(2)NPPh(2)](-) ligand which is ligated by two terminal P atoms and by one N atom.

KW - POLYFUNCTIONAL MOLECULES

KW - CHEMISTRY

KW - ANION

U2 - 10.1039/CC9960002095

DO - 10.1039/CC9960002095

M3 - Article

SN - 1359-7345

SP - 2095

EP - 2096

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

New phosphazene chains and ligands in complexes and clusters

Abstract

Keywords

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