New methods and applications in solid-state NMR spectroscopy of quadrupolar nuclei

Sharon E Ashbrook, Scott Sneddon

Research output: Contribution to journalArticlepeer-review

87 Citations (Scopus)
3 Downloads (Pure)

Abstract

Solid-state nuclear magnetic resonance (NMR) spectroscopy has long been established as offering unique atomic-scale and element-specific insight into the structure, disorder, and dynamics of materials. NMR spectra of quadrupolar nuclei (I > (1)/2) are often perceived as being challenging to acquire and to interpret because of the presence of anisotropic broadening arising from the interaction of the electric field gradient and the nuclear electric quadrupole moment, which broadens the spectral lines, often over several megahertz. Despite the vast amount of information contained in the spectral line shapes, the problems with sensitivity and resolution have, until very recently, limited the application of NMR spectroscopy of quadrupolar nuclei in the solid state. In this Perspective, we provide a brief overview of the quadrupolar interaction, describe some of the basic experimental approaches used for acquiring high-resolution NMR spectra, and discuss the information that these spectra can provide. We then describe some interesting recent examples to showcase some of the more exciting and challenging new applications of NMR spectra of quadrupolar nuclei in the fields of energy materials, microporous materials, Earth sciences, and biomaterials. Finally, we consider the possible directions that this highly informative technique may take in the future.
Original languageEnglish
Pages (from-to)15440-56
Number of pages17
JournalJournal of the American Chemical Society
Volume136
Issue number44
Early online date8 Oct 2014
DOIs
Publication statusPublished - 5 Nov 2014

Fingerprint

Dive into the research topics of 'New methods and applications in solid-state NMR spectroscopy of quadrupolar nuclei'. Together they form a unique fingerprint.

Cite this