New insight into the mechanism of the reaction between a,b-unsaturated carbonyl compounds and triethylborane (Brown's Reaction),

V Beraud; Y Gnanou; John Christopher Walton; B Maillard

New insight into the mechanism of the reaction between a,b-unsaturated carbonyl compounds and triethylborane (Brown's Reaction),

V Beraud
, Y Gnanou
, John Christopher Walton
, B Maillard

Research output: Contribution to journal › Article › peer-review

Abstract

A study of the reaction of alpha,beta-unsaturated carbonyl compounds with triethylborane under free radical conditions (Brown's reaction) including spectroscopic analyses (B-11 NMR, IR, EPR) of products and intermediates indicated that these reactions involve the prior formation of an 'alpha,beta-unsaturated carbonyl compound-organoborane' complex. (C) 2000 Elsevier Science Ltd. All rights reserved.

Original language	English
Pages (from-to)	1195-1198
Number of pages	4
Journal	Tetrahedron Letters
Volume	41
Publication status	Published - 19 Feb 2000

Keywords

boron and compounds
complexation
carbonyl compounds
enones
radicals and radical reactions
RADICALS

Handle.net

Persistent link

Cite this

@article{2134905ca85148e28c6e41c85da0a489,

title = "New insight into the mechanism of the reaction between a,b-unsaturated carbonyl compounds and triethylborane (Brown's Reaction),",

abstract = "A study of the reaction of alpha,beta-unsaturated carbonyl compounds with triethylborane under free radical conditions (Brown's reaction) including spectroscopic analyses (B-11 NMR, IR, EPR) of products and intermediates indicated that these reactions involve the prior formation of an 'alpha,beta-unsaturated carbonyl compound-organoborane' complex. (C) 2000 Elsevier Science Ltd. All rights reserved.",

keywords = "boron and compounds, complexation, carbonyl compounds, enones, radicals and radical reactions, RADICALS",

author = "V Beraud and Y Gnanou and Walton, \{John Christopher\} and B Maillard",

year = "2000",

month = feb,

day = "19",

language = "English",

volume = "41",

pages = "1195--1198",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier",

}

TY - JOUR

T1 - New insight into the mechanism of the reaction between a,b-unsaturated carbonyl compounds and triethylborane (Brown's Reaction),

AU - Beraud, V

AU - Gnanou, Y

AU - Walton, John Christopher

AU - Maillard, B

PY - 2000/2/19

Y1 - 2000/2/19

N2 - A study of the reaction of alpha,beta-unsaturated carbonyl compounds with triethylborane under free radical conditions (Brown's reaction) including spectroscopic analyses (B-11 NMR, IR, EPR) of products and intermediates indicated that these reactions involve the prior formation of an 'alpha,beta-unsaturated carbonyl compound-organoborane' complex. (C) 2000 Elsevier Science Ltd. All rights reserved.

AB - A study of the reaction of alpha,beta-unsaturated carbonyl compounds with triethylborane under free radical conditions (Brown's reaction) including spectroscopic analyses (B-11 NMR, IR, EPR) of products and intermediates indicated that these reactions involve the prior formation of an 'alpha,beta-unsaturated carbonyl compound-organoborane' complex. (C) 2000 Elsevier Science Ltd. All rights reserved.

KW - boron and compounds

KW - complexation

KW - carbonyl compounds

KW - enones

KW - radicals and radical reactions

KW - RADICALS

UR - https://www.scopus.com/pages/publications/0034685208

M3 - Article

SN - 0040-4039

VL - 41

SP - 1195

EP - 1198

JO - Tetrahedron Letters

JF - Tetrahedron Letters

ER -

New insight into the mechanism of the reaction between a,b-unsaturated carbonyl compounds and triethylborane (Brown's Reaction),

Abstract

Keywords

Handle.net

Other files and links

Fingerprint

Cite this