New insight into the mechanism of the reaction between a,b-unsaturated carbonyl compounds and triethylborane (Brown's Reaction),

V Beraud; Y Gnanou; John Christopher Walton; B Maillard

New insight into the mechanism of the reaction between a,b-unsaturated carbonyl compounds and triethylborane (Brown's Reaction),

V Beraud, Y Gnanou, John Christopher Walton, B Maillard

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

A study of the reaction of alpha,beta-unsaturated carbonyl compounds with triethylborane under free radical conditions (Brown's reaction) including spectroscopic analyses (B-11 NMR, IR, EPR) of products and intermediates indicated that these reactions involve the prior formation of an 'alpha,beta-unsaturated carbonyl compound-organoborane' complex. (C) 2000 Elsevier Science Ltd. All rights reserved.

Original language	English
Pages (from-to)	1195-1198
Number of pages	4
Journal	Tetrahedron Letters
Volume	41
Publication status	Published - 19 Feb 2000

Keywords

boron and compounds
complexation
carbonyl compounds
enones
radicals and radical reactions
RADICALS

Cite this

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abstract = "A study of the reaction of alpha,beta-unsaturated carbonyl compounds with triethylborane under free radical conditions (Brown's reaction) including spectroscopic analyses (B-11 NMR, IR, EPR) of products and intermediates indicated that these reactions involve the prior formation of an 'alpha,beta-unsaturated carbonyl compound-organoborane' complex. (C) 2000 Elsevier Science Ltd. All rights reserved.",

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AU - Beraud, V

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AU - Walton, John Christopher

AU - Maillard, B

PY - 2000/2/19

Y1 - 2000/2/19

N2 - A study of the reaction of alpha,beta-unsaturated carbonyl compounds with triethylborane under free radical conditions (Brown's reaction) including spectroscopic analyses (B-11 NMR, IR, EPR) of products and intermediates indicated that these reactions involve the prior formation of an 'alpha,beta-unsaturated carbonyl compound-organoborane' complex. (C) 2000 Elsevier Science Ltd. All rights reserved.

AB - A study of the reaction of alpha,beta-unsaturated carbonyl compounds with triethylborane under free radical conditions (Brown's reaction) including spectroscopic analyses (B-11 NMR, IR, EPR) of products and intermediates indicated that these reactions involve the prior formation of an 'alpha,beta-unsaturated carbonyl compound-organoborane' complex. (C) 2000 Elsevier Science Ltd. All rights reserved.

KW - boron and compounds

KW - complexation

KW - carbonyl compounds

KW - enones

KW - radicals and radical reactions

KW - RADICALS

UR - http://www.scopus.com/inward/record.url?scp=0034685208&partnerID=8YFLogxK

M3 - Article

SN - 0040-4039

VL - 41

SP - 1195

EP - 1198

JO - Tetrahedron Letters

JF - Tetrahedron Letters

ER -

New insight into the mechanism of the reaction between a,b-unsaturated carbonyl compounds and triethylborane (Brown's Reaction),

Abstract

Keywords

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