New [Au(NHC)(OH)] complexes for silver-free protocols

Scott Robert Patrick; Adrian Gomez Suarez; Alexandra Martha Zoya Slawin; Steven Patrick Nolan

doi:10.1021/om4010065

New [Au(NHC)(OH)] complexes for silver-free protocols

Scott Robert Patrick, Adrian Gomez Suarez, Alexandra Martha Zoya Slawin, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

Novel (NHC)gold(I) hydroxides are reported. Their differing tolerances to air and moisture are rationalized by the varying abilities of the NHC ligands to sterically protect the reactive metal center. A number of gold hydroxides were used in the silver-free preparation of Gagosz-type catalysts. This general procedure led to analytically pure products while avoiding the use of expensive silver reagents.

Original language	English
Pages (from-to)	421-424
Number of pages	4
Journal	Organometallics
Volume	33
Issue number	1
Early online date	11 Dec 2013
DOIs	https://doi.org/10.1021/om4010065
Publication status	Published - 13 Jan 2014

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10.1021/om4010065

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title = "New [Au(NHC)(OH)] complexes for silver-free protocols",

abstract = "Novel (NHC)gold(I) hydroxides are reported. Their differing tolerances to air and moisture are rationalized by the varying abilities of the NHC ligands to sterically protect the reactive metal center. A number of gold hydroxides were used in the silver-free preparation of Gagosz-type catalysts. This general procedure led to analytically pure products while avoiding the use of expensive silver reagents.",

author = "Patrick, \{Scott Robert\} and \{Gomez Suarez\}, Adrian and Slawin, \{Alexandra Martha Zoya\} and Nolan, \{Steven Patrick\}",

note = "This work is supported by the ERC (Advanced Investigator Award-FUNCAT) and the EPSRC",

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AU - Gomez Suarez, Adrian

AU - Slawin, Alexandra Martha Zoya

AU - Nolan, Steven Patrick

N1 - This work is supported by the ERC (Advanced Investigator Award-FUNCAT) and the EPSRC

PY - 2014/1/13

Y1 - 2014/1/13

N2 - Novel (NHC)gold(I) hydroxides are reported. Their differing tolerances to air and moisture are rationalized by the varying abilities of the NHC ligands to sterically protect the reactive metal center. A number of gold hydroxides were used in the silver-free preparation of Gagosz-type catalysts. This general procedure led to analytically pure products while avoiding the use of expensive silver reagents.

AB - Novel (NHC)gold(I) hydroxides are reported. Their differing tolerances to air and moisture are rationalized by the varying abilities of the NHC ligands to sterically protect the reactive metal center. A number of gold hydroxides were used in the silver-free preparation of Gagosz-type catalysts. This general procedure led to analytically pure products while avoiding the use of expensive silver reagents.

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JO - Organometallics

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IS - 1

ER -

New [Au(NHC)(OH)] complexes for silver-free protocols

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Synthesis and reactivity of novel (NHC)gold(I) complexes

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New [Au(NHC)(OH)] complexes for silver-free protocols

Abstract

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Student theses

Synthesis and reactivity of novel (NHC)gold(I) complexes

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