New [Au(NHC)(OH)] complexes for silver-free protocols

Scott Robert Patrick, Adrian Gomez Suarez, Alexandra Martha Zoya Slawin, Steven Patrick Nolan

Research output: Contribution to journalArticlepeer-review

32 Citations (Scopus)

Abstract

Novel (NHC)gold(I) hydroxides are reported. Their differing tolerances to air and moisture are rationalized by the varying abilities of the NHC ligands to sterically protect the reactive metal center. A number of gold hydroxides were used in the silver-free preparation of Gagosz-type catalysts. This general procedure led to analytically pure products while avoiding the use of expensive silver reagents.
Original languageEnglish
Pages (from-to)421-424
Number of pages4
JournalOrganometallics
Volume33
Issue number1
Early online date11 Dec 2013
DOIs
Publication statusPublished - 13 Jan 2014

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