[N(CH3)4]2[Co2Mo 6O12(OH)4(PO4)(HPO4) 2-(H2PO4)].5H2O, a new one-dimensional molybdenum phosphate

Philip Lightfoot; Diane Masson

doi:10.1107/S0108270195015551

[N(CH₃)₄]₂[Co₂Mo ₆O₁₂(OH)₄(PO₄)(HPO₄) ₂-(H₂PO₄)].5H₂O, a new one-dimensional molybdenum phosphate

Philip Lightfoot^*, Diane Masson

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, bis(tetramethylaramonium) dicobaltio - μ-dihydrogenphosphato -μ- bis (hydrogenphosphato)-μ ₆-phosphato-tetrahydroxycyclohexamolybdate-(Mo-Mo) pentahydrate, was synthesized hydrothermally and crystallizes as a polymeric ionic complex with anionic chains, composed of [Mo₆O₁₂(OH)₃(H_xPO₄) ₄]^n- clusters held together by Co²⁺ cations running parallel to the b axis. Neighbouring chains are linked by hydrogen bonds only via intervening [N(CH₃)4]⁺ cations and water molecules.

Original language	English
Pages (from-to)	1077-1080
Number of pages	4
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	52
Issue number	5
DOIs	https://doi.org/10.1107/S0108270195015551
Publication status	Published - 15 May 1996

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@article{1f74cf1e0b4f4c8abd6a8b5159893a48,

title = "[N(CH3)4]2[Co2Mo 6O12(OH)4(PO4)(HPO4) 2-(H2PO4)].5H2O, a new one-dimensional molybdenum phosphate",

abstract = "The title compound, bis(tetramethylaramonium) dicobaltio - μ-dihydrogenphosphato -μ- bis (hydrogenphosphato)-μ 6-phosphato-tetrahydroxycyclohexamolybdate-(Mo-Mo) pentahydrate, was synthesized hydrothermally and crystallizes as a polymeric ionic complex with anionic chains, composed of [Mo6O12(OH)3(HxPO4) 4]n- clusters held together by Co2+ cations running parallel to the b axis. Neighbouring chains are linked by hydrogen bonds only via intervening [N(CH3)4]+ cations and water molecules.",

author = "Philip Lightfoot and Diane Masson",

year = "1996",

month = may,

day = "15",

doi = "10.1107/S0108270195015551",

language = "English",

volume = "52",

pages = "1077--1080",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "5",

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TY - JOUR

T1 - [N(CH3)4]2[Co2Mo 6O12(OH)4(PO4)(HPO4) 2-(H2PO4)].5H2O, a new one-dimensional molybdenum phosphate

AU - Lightfoot, Philip

AU - Masson, Diane

PY - 1996/5/15

Y1 - 1996/5/15

N2 - The title compound, bis(tetramethylaramonium) dicobaltio - μ-dihydrogenphosphato -μ- bis (hydrogenphosphato)-μ 6-phosphato-tetrahydroxycyclohexamolybdate-(Mo-Mo) pentahydrate, was synthesized hydrothermally and crystallizes as a polymeric ionic complex with anionic chains, composed of [Mo6O12(OH)3(HxPO4) 4]n- clusters held together by Co2+ cations running parallel to the b axis. Neighbouring chains are linked by hydrogen bonds only via intervening [N(CH3)4]+ cations and water molecules.

AB - The title compound, bis(tetramethylaramonium) dicobaltio - μ-dihydrogenphosphato -μ- bis (hydrogenphosphato)-μ 6-phosphato-tetrahydroxycyclohexamolybdate-(Mo-Mo) pentahydrate, was synthesized hydrothermally and crystallizes as a polymeric ionic complex with anionic chains, composed of [Mo6O12(OH)3(HxPO4) 4]n- clusters held together by Co2+ cations running parallel to the b axis. Neighbouring chains are linked by hydrogen bonds only via intervening [N(CH3)4]+ cations and water molecules.

UR - https://www.scopus.com/pages/publications/0030145666

U2 - 10.1107/S0108270195015551

DO - 10.1107/S0108270195015551

M3 - Article

AN - SCOPUS:0030145666

SN - 0108-2701

VL - 52

SP - 1077

EP - 1080

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 5

ER -

[N(CH₃)₄]₂[Co₂Mo ₆O₁₂(OH)₄(PO₄)(HPO₄) ₂-(H₂PO₄)].5H₂O, a new one-dimensional molybdenum phosphate

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