[N(CH3)4]2[Co2Mo 6O12(OH)4(PO4)(HPO4) 2-(H2PO4)].5H2O, a new one-dimensional molybdenum phosphate

Philip Lightfoot*, Diane Masson

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

42 Citations (Scopus)

Abstract

The title compound, bis(tetramethylaramonium) dicobaltio - μ-dihydrogenphosphato -μ- bis (hydrogenphosphato)-μ 6-phosphato-tetrahydroxycyclohexamolybdate-(Mo-Mo) pentahydrate, was synthesized hydrothermally and crystallizes as a polymeric ionic complex with anionic chains, composed of [Mo6O12(OH)3(HxPO4) 4]n- clusters held together by Co2+ cations running parallel to the b axis. Neighbouring chains are linked by hydrogen bonds only via intervening [N(CH3)4]+ cations and water molecules.

Original languageEnglish
Pages (from-to)1077-1080
Number of pages4
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume52
Issue number5
DOIs
Publication statusPublished - 15 May 1996

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