Na2MoO2−δF4+δ – a perovskite with a unique combination of atomic orderings and octahedral tilts

Hajime Ishikawa; Irene Munao'; Bela Ernest Bode; Zenji Hiroi; Philip Lightfoot

doi:10.1039/C5CC05446J

Na₂MoO_2−δF_4+δ– a perovskite with a unique combination of atomic orderings and octahedral tilts

Hajime Ishikawa, Irene Munao', Bela Ernest Bode, Zenji Hiroi, Philip Lightfoot

Research output: Contribution to journal › Article › peer-review

Abstract

Na₂MoO_2−δF_4+δ (δ ∼ 0.08) displays a unique variant of the perovskite structure, with simultaneous (Na,vacancy) ordering on the A-site, (Na,Mo) ordering on the B-site, (O,F) ordering on the anion site and an unusual NaNbO₃-like octahedral tilt system.

Original language	English
Pages (from-to)	15469-15471
Journal	Chemical Communications
Volume	51
Issue number	84
Early online date	3 Sept 2015
DOIs	https://doi.org/10.1039/C5CC05446J
Publication status	Published - 28 Oct 2015

Access to Document

10.1039/C5CC05446JLicence: CC BY

Bode_2015_ChemComm_Na2MoO2_CC
Copyright 2015 the Authors. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (http://creativecommons.org/licenses/by/3.0/).
Final published version, 1.84 MBLicence: CC BY

Cite this

@article{8376566d14d1470788d660a49794a82f,

title = "Na2MoO2−δF4+δ – a perovskite with a unique combination of atomic orderings and octahedral tilts",

abstract = "Na2MoO2−δF4+δ (δ ∼ 0.08) displays a unique variant of the perovskite structure, with simultaneous (Na,vacancy) ordering on the A-site, (Na,Mo) ordering on the B-site, (O,F) ordering on the anion site and an unusual NaNbO3-like octahedral tilt system.",

author = "Hajime Ishikawa and Irene Munao' and Bode, {Bela Ernest} and Zenji Hiroi and Philip Lightfoot",

note = "The authors acknowledge EPSRC (EP/K503162/1) for funding this research. ",

year = "2015",

month = oct,

day = "28",

doi = "10.1039/C5CC05446J",

language = "English",

volume = "51",

pages = "15469--15471",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "84",

}

TY - JOUR

T1 - Na2MoO2−δF4+δ – a perovskite with a unique combination of atomic orderings and octahedral tilts

AU - Ishikawa, Hajime

AU - Munao', Irene

AU - Bode, Bela Ernest

AU - Hiroi, Zenji

AU - Lightfoot, Philip

N1 - The authors acknowledge EPSRC (EP/K503162/1) for funding this research.

PY - 2015/10/28

Y1 - 2015/10/28

N2 - Na2MoO2−δF4+δ (δ ∼ 0.08) displays a unique variant of the perovskite structure, with simultaneous (Na,vacancy) ordering on the A-site, (Na,Mo) ordering on the B-site, (O,F) ordering on the anion site and an unusual NaNbO3-like octahedral tilt system.

AB - Na2MoO2−δF4+δ (δ ∼ 0.08) displays a unique variant of the perovskite structure, with simultaneous (Na,vacancy) ordering on the A-site, (Na,Mo) ordering on the B-site, (O,F) ordering on the anion site and an unusual NaNbO3-like octahedral tilt system.

UR - http://www.rsc.org/suppdata/c5/cc/c5cc05446j/c5cc05446j1.txt

UR - http://www.rsc.org/suppdata/c5/cc/c5cc05446j/c5cc05446j2.pdf

UR - http://www.rsc.org/suppdata/c5/cc/c5cc05446j/c5cc05446j3.cif

U2 - 10.1039/C5CC05446J

DO - 10.1039/C5CC05446J

M3 - Article

SN - 1359-7345

VL - 51

SP - 15469

EP - 15471

JO - Chemical Communications

JF - Chemical Communications

IS - 84

ER -

Na₂MoO_2−δF_4+δ– a perovskite with a unique combination of atomic orderings and octahedral tilts

Abstract

Access to Document

Other files and links

Fingerprint

Data Underpinning Article: Na2MoO2-dF4+d – a perovskite with a unique combination of atomic orderings and octahedral tilts

Cite this

Na2MoO2−δF4+δ – a perovskite with a unique combination of atomic orderings and octahedral tilts

Abstract

Access to Document

Other files and links

Fingerprint

Datasets

Data Underpinning Article: Na2MoO2-dF4+d – a perovskite with a unique combination of atomic orderings and octahedral tilts

Cite this

Na₂MoO_2−δF_4+δ– a perovskite with a unique combination of atomic orderings and octahedral tilts