N-Heterocyclic Carbene-Ruthenium Complexes for the Racemization of Chiral Alcohols

Johann Bosson; Steven Patrick Nolan

doi:10.1021/jo1001005

N-Heterocyclic Carbene-Ruthenium Complexes for the Racemization of Chiral Alcohols

Johann Bosson, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

The activity of well-defined 16-electron ruthenium complexes bearing an N-heterocyclic carbene ligand in the racemization of chiral alcohols is reported. Mechanistic considerations are also presented.

Original language	English
Pages (from-to)	2039-2043
Number of pages	5
Journal	The Journal of Organic Chemistry
Volume	75
Issue number	6
DOIs	https://doi.org/10.1021/jo1001005
Publication status	Published - 19 Mar 2010

Keywords

DYNAMIC KINETIC RESOLUTION
ASYMMETRIC TRANSFER HYDROGENATION
TERTIARY PHOSPHINE-LIGANDS
RUCL CP-ASTERISK
SECONDARY ALCOHOLS
CATALYTIC RACEMIZATION
NUCLEOPHILIC CARBENE
AMBIENT-TEMPERATURE
ENZYMATIC RESOLUTION
ETA(5)-C5ME5 MOIETY

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10.1021/jo1001005

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title = "N-Heterocyclic Carbene-Ruthenium Complexes for the Racemization of Chiral Alcohols",

abstract = "The activity of well-defined 16-electron ruthenium complexes bearing an N-heterocyclic carbene ligand in the racemization of chiral alcohols is reported. Mechanistic considerations are also presented.",

keywords = "DYNAMIC KINETIC RESOLUTION, ASYMMETRIC TRANSFER HYDROGENATION, TERTIARY PHOSPHINE-LIGANDS, RUCL CP-ASTERISK, SECONDARY ALCOHOLS, CATALYTIC RACEMIZATION, NUCLEOPHILIC CARBENE, AMBIENT-TEMPERATURE, ENZYMATIC RESOLUTION, ETA(5)-C5ME5 MOIETY",

author = "Johann Bosson and Nolan, {Steven Patrick}",

year = "2010",

month = mar,

day = "19",

doi = "10.1021/jo1001005",

language = "English",

volume = "75",

pages = "2039--2043",

journal = "The Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society (ACS)",

number = "6",

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TY - JOUR

T1 - N-Heterocyclic Carbene-Ruthenium Complexes for the Racemization of Chiral Alcohols

AU - Bosson, Johann

AU - Nolan, Steven Patrick

PY - 2010/3/19

Y1 - 2010/3/19

N2 - The activity of well-defined 16-electron ruthenium complexes bearing an N-heterocyclic carbene ligand in the racemization of chiral alcohols is reported. Mechanistic considerations are also presented.

AB - The activity of well-defined 16-electron ruthenium complexes bearing an N-heterocyclic carbene ligand in the racemization of chiral alcohols is reported. Mechanistic considerations are also presented.

KW - DYNAMIC KINETIC RESOLUTION

KW - ASYMMETRIC TRANSFER HYDROGENATION

KW - TERTIARY PHOSPHINE-LIGANDS

KW - RUCL CP-ASTERISK

KW - SECONDARY ALCOHOLS

KW - CATALYTIC RACEMIZATION

KW - NUCLEOPHILIC CARBENE

KW - AMBIENT-TEMPERATURE

KW - ENZYMATIC RESOLUTION

KW - ETA(5)-C5ME5 MOIETY

UR - http://www.scopus.com/inward/record.url?scp=77949808439&partnerID=8YFLogxK

U2 - 10.1021/jo1001005

DO - 10.1021/jo1001005

M3 - Article

SN - 0022-3263

VL - 75

SP - 2039

EP - 2043

JO - The Journal of Organic Chemistry

JF - The Journal of Organic Chemistry

IS - 6

ER -

N-Heterocyclic Carbene-Ruthenium Complexes for the Racemization of Chiral Alcohols

Abstract

Keywords

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